[(2-(2',6'-difluorophenyl)-1,10-phenanthroline)Pd(NCCH3)Cl][OTf] | 1272029-60-3

• 英文名称: [(2-(2',6'-difluorophenyl)-1,10-phenanthroline)Pd(NCCH3)Cl][OTf]
• CAS: 1272029-60-3
• 化学式: CF₃O₃S*C₂₀H₁₃ClF₂N₃Pd
• 分子量: 624.284
• InChiKey: RDROXKACTAECDC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 2-(2',6'-difluorophenyl)-1,10-phenanthroline 、 silver trifluoromethanesulfonate 以 乙腈 为溶剂， 以10%的产率得到[(2-(2',6'-difluorophenyl)-1,10-phenanthroline)Pd(NCCH3)Cl][OTf]
  参考文献：
  名称：

  Oxidatively Resistant Ligands for Palladium-Catalyzed Aerobic Alcohol Oxidation

  摘要：

  The complex [(neocuproine)Pd(OAc)](2)[OTf](2) (1) catalyzes the aerobic oxidation of 2-heptanol at room temperature, but Competitive ligand oxidation leads to low catalyst lifetimes. In an effort to mitigate the oxidative degradation of the ligand, a variety of Pd complexes ligated by fluorinated phenanthrolines (bis-2,9-(trifluoromethyl)-1,10-phenanthroline (btfm-phen), 4-methyl-2-(trifluoromethyl)-1,10-phenanthroline (tfmm-phen), and 2-(o-difluoropheny1)-1,10-phenanthroline (odfp-phen)) were prepared and tested. Active catalyst precursors were generated by in situ conproportionation of (N- N)Pd(OAc)(2) and [(N-N)Pd(NCCH3)(2)[OTf](2). Pd complexes derived from tfmm-phen catalyzed the aerobic oxidation of 2-heptanol at room temperature with up to 22 turnovers, nearly double that of 1.

  DOI：

  10.1021/om101037k