mer-[CrCl(H2NCMe2CH2NH2)(H2N(CH2)3NH(CH2)3NH2)](2+) | 137705-00-1

• 英文名称: mer-[CrCl(H2NCMe2CH2NH2)(H2N(CH2)3NH(CH2)3NH2)](2+)
• CAS: 137705-00-1
• 化学式: C₁₀H₂₉ClCrN₅
• 分子量: 306.823
• InChiKey: ZUEDZOQTZFIUIO-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  mer-[CrCl(H2NCMe2CH2NH2)(H2N(CH2)3NH(CH2)3NH2)](2+) 在 水 、 mercury(II) nitrate 作用下， 以 高氯酸 为溶剂， 生成
  参考文献：
  名称：

  Pressure effects on the rates of Hg2+-assisted chloride release from some [CrCl(diamine)(triamine)]2+ complexes

  摘要：

  The rate of Hg2+-assisted chloride release from several mer-[CrCl(diamine)(triamine)](2+) complexes has been measured as a function of pressure, Hg2+ concentration and temperature. The calculated activation volumes are independent of [Hg2+] and temperature and kinetic parameters 10(4) k(Hg) (25 degrees C) (M(-1) s(-1)), Delta H double dagger (kJ mol(-1)), Delta S double dagger (J K-1 mol(-1)), Delta V double dagger (cc mol(-1)) are: (en)(dpt): 6.44, 75.5, -53, -5.0; (ibn)(dpt): 5.81, 89.5, -6, -0.03; (Me(2)tn)(dpt): 22.2, 84.9, -11, -0.5; (tn)(dpt): 29.1, 87, -1, +0.3; (en)(2,3-tri): 1.94, 87.0, -24, -5.7; (en)(Medpt): 0.417, 94.6, -11, -0.8; (tn)(Medpt): 9.14, 98.3, +26, +1.8.

  DOI：

  10.1016/0020-1693(94)04300-k