Diruthenium, diiron and mixed ruthenium–iron tetraiminediphenolate macrocyclic complexes: Synthetic route, spectroscopy, molecular mechanics and redox properties
摘要:
A series of diruthenium(II), [Ru-2(tidf)CI2(H2O)(2)]center dot H2O, diiron(II) [Fe-2(tidf)(MeOH)(4)](CIO4)(2) and mixed ruthenium(II)-iron(II) [Ru(MeOH)(2)FeC1(H2O)(tidf)](CIO4) (tidf= a two compartment tetraiminediphenolate macrocycle) complexes were prepared and characterized by elemental analysis, FTIR, UV-vis, cyclic voltammetry and semi-empirical molecular mechanics calculations. (c) 2006 Elsevier B.V. All rights reserved.