11-butyl-5-phenoxy-5-phenyl-5,10,11,12-tetrahydro-5l5-benzo[c]benzo[3,4][1,2]azasilolo[1,2-a][1,2]azasilol-11-ium | 1236291-77-2

• 英文名称: 11-butyl-5-phenoxy-5-phenyl-5,10,11,12-tetrahydro-5l5-benzo[c]benzo[3,4][1,2]azasilolo[1,2-a][1,2]azasilol-11-ium
• CAS: 1236291-77-2
• 化学式: C₃₀H₃₁NOSi
• 分子量: 449.668
• InChiKey: VQGMNMFRYNXCAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 苯酚 以 氯仿 为溶剂， 反应 13.0h， 以84%的产率得到11-butyl-5-phenoxy-5-phenyl-5,10,11,12-tetrahydro-5l5-benzo[c]benzo[3,4][1,2]azasilolo[1,2-a][1,2]azasilol-11-ium
  参考文献：
  名称：

  Synthesis and Properties of Pentacoordinated Phenoxysilane and Carboxysilanes with Intramolecular Nitrogen–Silicon Coordination

  摘要：

  Reactions of a neutral pentacoordinated monohydrosilane bearing a dative N-Si bond with phenol and benzoic acid derivatives gave the corresponding pentacoordinated phenoxysilane and carboxysilanes, respectively. X-ray crystallographic analyses of these silanes revealed that the distance of the N-Si dative bond is shortened and the pentacoordination character of the silicon center becomes greater with the increase in the electron-withdrawing character of the apical substituent on silicon.

  DOI：

  10.1080/10426501003773746