(C5H5)Ru(PPh3)(μ-I)(μ-PPh2CH2PPh2)PdI2 | 943527-85-3

• 英文名称: (C5H5)Ru(PPh3)(μ-I)(μ-PPh2CH2PPh2)PdI2
• CAS: 943527-85-3
• 化学式: C₄₈H₄₂I₃P₃PdRu
• 分子量: 1299.99
• InChiKey: PIVBALUKUIYHFB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η5-C5H5)Ru(II)(PPh3)(η1-dppm)I 、 (1Z,5Z)-cycloocta-1,5-diene;diiodopalladium 、 sodium iodide 以 二氯甲烷 为溶剂， 以63.5%的产率得到(C5H5)Ru(PPh3)(μ-I)(μ-PPh2CH2PPh2)PdI2
  参考文献：
  名称：

  Electronic Interactions in Iron- and Ruthenium-Containing Heterobimetallic Complexes:  Structural and Spectroscopic Investigations

  摘要：

  The heterobimetallic Ru complexes Cp(CO)Ru(mu-I)(mu-dppm)PtI2 (8), Cp(CO)Ru(mu-I)(mu-dppm)PdI2 (10), and Cp(CO)RuI(mu-dppm)AuI (12) and their isoelectronic Fe analogues Cp(CO)Fe(mu-I)(mu-dppm)PtI2 (9), Cp(CO)Fe(mu-I)(mu-dppm)PdI2 (11), and Cp(CO)FeI(mu-dppm)AuI (13) were prepared by the reactions of Cp(CO)M(kappa(1)-dppm)I (6, M = Ru; 7, M = Fe) with Pt(COD)I-2, Pd(COD)I-2, and AuI, respectively. All six complexes were characterized by cyclic voltammetry, IR, UV, and NMR (H-1 and P-31) spectroscopy, and elemental analysis. The structures of the I-bridged compounds 8-11 were determined by X-ray crystallography. Electronic interaction between the two metals is significant for the iodide-bridged compounds 8-11, as evidenced by the variation in their carbonyl stretching frequencies and UV-vis spectra, as well as in the shifts of their redox potentials in comparison to the shifts for mononuclear model compounds. In contrast, compounds 12 and 13, which have only dppm bridges, exhibit limited interactions between the two metals.

  DOI：

  10.1021/om0610750