cis-[Ru(NO)Cl4(CH3CN)](1-) | 171020-29-4

• 英文名称: cis-[Ru(NO)Cl4(CH3CN)](1-)
• CAS: 171020-29-4
• 化学式: C₂H₃Cl₄N₂ORu
• 分子量: 313.941
• InChiKey: KVPDPNOJDMUAPP-UHFFFAOYSA-J

反应信息

• 作为反应物：
  描述：

  cis-[Ru(NO)Cl4(CH3CN)](1-) 以 乙腈 为溶剂， 以58%的产率得到trans-{N(C4H9)4}{RuCl4(CH3CN)2}
  参考文献：
  名称：

  Successive Chemical Reactions Accompanying a One-Electron Oxidation of a {MNO}⁶-Type Nitrosyl Complex, Pentachloro(nitrosyl)ruthenate(2−), and a Characterization of the Product Species

  摘要：

  A one-electron oxidation species of the title complex, [Ru(NO)Cl5]−({RuNO}5-type nitrosyl complex), converted into cis-[Ru(NO)Cl4(CH3CN)]−({RuNO}6-type nitrosyl complex) at low temperature (5 °C) in the dark. The product species could be isolated and characterized. An X-ray structure determination showed a remarkably short N–O bond distance of the Ru–NO moiety: l(N–O) = 0.998 Å, l(Ru–N) = 1.787(5) Å, ∠Ru–N–O = 175.1(6)°. Under room light at 25 °C, the complex underwent a facile nitrosyl photoelimination to give trans-[RuCl4(CH3CN)2]−, the structure of which was also established. During the course of the reactions, two other unidentified species were confirmed to exist by cyclic voltammetry.

  DOI：

  10.1246/bcsj.68.2897
• 作为产物：
  描述：

  Azanylidyneoxidanium;ruthenium(3+);pentachloride 以 乙腈 为溶剂， 生成 cis-[Ru(NO)Cl4(CH3CN)](1-)
  参考文献：
  名称：

  Successive Chemical Reactions Accompanying a One-Electron Oxidation of a {MNO}⁶-Type Nitrosyl Complex, Pentachloro(nitrosyl)ruthenate(2−), and a Characterization of the Product Species

  摘要：

  A one-electron oxidation species of the title complex, [Ru(NO)Cl5]−({RuNO}5-type nitrosyl complex), converted into cis-[Ru(NO)Cl4(CH3CN)]−({RuNO}6-type nitrosyl complex) at low temperature (5 °C) in the dark. The product species could be isolated and characterized. An X-ray structure determination showed a remarkably short N–O bond distance of the Ru–NO moiety: l(N–O) = 0.998 Å, l(Ru–N) = 1.787(5) Å, ∠Ru–N–O = 175.1(6)°. Under room light at 25 °C, the complex underwent a facile nitrosyl photoelimination to give trans-[RuCl4(CH3CN)2]−, the structure of which was also established. During the course of the reactions, two other unidentified species were confirmed to exist by cyclic voltammetry.

  DOI：

  10.1246/bcsj.68.2897