四羟基钯 | 81931-07-9

• 中文名称: 四羟基钯
• 英文名称: tetrahydroxypalladium
• 英文别名: palladium (IV) hydroxide；palladium(IV) hydroxide
• CAS: 81931-07-9
• 化学式: H₄O₄Pd
• 分子量: 174.449
• InChiKey: DWDXKBXWXNKWOX-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -2.23
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.92
• 氢给体数：
  4.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  morpholinium tetrachloropalladate(II) 以 水 为溶剂， 反应 24.0h， 生成 四羟基钯
  参考文献：
  名称：

  Cationic–anionic palladium complexes: effect of hydrogen bond character on their stability and biological activity

  摘要：

  The solution state of palladium cationic-anionic complexes (AmH (n) ) (k) [PdCl4] prepared for the first time, where Am is morpholine, methylmorpholine, aminoethylmorpholine, 5-aminovaleric acid, L-1-phenyl-2-methylaminopropanol, and m-xylilenediamine, has been studied by electronic absorption spectroscopy, NMR, and pH measurements. The agreement of obtained results for the state of the complexes in water and NaCl solutions with IR and X-ray diffraction data for these complexes has allowed us to substantiate the principle for designing patent formulation (C5H12NO)(2)[PdCl4], a new type of palladium complexes, palladium(II) cationic-anionic complexes showing high antitumor and antimetastatic activity. Crystallographic data for six obtained complexes have been presented.

  DOI：

  10.1134/s0036023617110043

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: O: MVol.4, 91, page 1182 - 1184
  作者：

  DOI：——

  日期：——
• Woehler, L.; Koenig, J., Zeitschrift fur anorganische Chemie, 1905, vol. 46, p. 323 - 349
  作者：Woehler, L.、Koenig, J.

  DOI：——

  日期：——