[(MeCN)2Mo(CO)2(η(3)-CH2CMeCH2)] | 196932-51-1

• 英文名称: [(MeCN)2Mo(CO)2(η(3)-CH2CMeCH2)]
• CAS: 196932-51-1
• 化学式: C₁₀H₁₃MoN₂O₂
• 分子量: 289.165
• InChiKey: RRNUPHAYFUHJLF-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [(MeCN)2Mo(CO)2(η(3)-CH2CMeCH2)] 、 Tl(hydrotris(3-cyclopropylpyrazol-1-yl)borate) 以 二氯甲烷 为溶剂， 生成 [Mo(hydrotris(3-cyclopropylpyrazol-1-yl)borate)(CO)2(η(3)-CH2CMeCH2)]
  参考文献：
  名称：

  Coordination Chemistry of Homoscorpionate Ligands with 3-Cyclopropyl Substituents

  摘要：

  In a quest for precisely sterically tuned ligand systems, the new scorpionate ligands hydrotris(3-cyclopropylpyrazol-1-yl)borate, Tp(Cpr), and tetrakis(3-cyclopropylpyrazol-1-yl)borate, pz*Tp(Cpr), have been synthesized. They readily form octahedral homoleptic and heteroleptic complexes with first-row transition metal compounds, but their [M(Tp(Cpr))(X)] complexes are unstable with respect to the octahedral ones. The complex [Mo(Tp(Cpr))(CO)(2)(eta(3)-CH2CMeCH2)] was also prepared. Structures of the paramagnetic [Co(Tp(Cpr))(2)], [Co(pz*Tp(Cpr))(2)], and [Co(Tp(Cpr))(Tp(Ph))] complexes have been determined by H-1 NMR and those of [Fe(Tp(Cpr))(2)] and [Fe(pz*Tp(Cpr))(2)], as well as that of [Co(Tp(Cpr))(Tp(Ph))], by X-ray crystallography, indicating facile accommodation of six cyclopropyl groups in the equatorial belt of octahedral complexes. In its coordination behavior, Tp(Cpr) is quite different from Tp(iPr) and resembles Tp(Me).

  DOI：

  10.1021/ic970880r

文献信息

• Rheingold, Arnold L.; Haggerty, Brian S.; Yap, Glenn P.A., Inorganic Chemistry, 1997, vol. 36, # 22, p. 5097 - 5103
  作者：Rheingold, Arnold L.、Haggerty, Brian S.、Yap, Glenn P.A.、Trofimenko, Swiatoslaw

  DOI：——

  日期：——