fac-Mn(CO)3(1,2-bis(diphenylphosphino)propane)(COOCH3) | 201486-92-2

• 英文名称: fac-Mn(CO)3(1,2-bis(diphenylphosphino)propane)(COOCH3)
• CAS: 201486-92-2
• 化学式: C₃₂H₂₉MnO₅P₂
• 分子量: 610.465
• InChiKey: AZWPQDTXQPMXLG-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  fac-Mn(CO)3(1,2-bis(diphenylphosphino)propane)(COOCH3) 在 H₂O 作用下， 以 二氯甲烷 为溶剂， 生成 Mn(CO)3(1,3-bis(diphenylphosphino)propane)(OCOO)Mn(CO)3(1,3-bis(diphenylphosphino)propane)
  参考文献：
  名称：

  Conversion of a manganese-carbon-bonded complex to a manganese-oxygen-bonded complex, some reactions of manganese carbonato complexes

  摘要：

  Stirring a solution of the manganese carboxylate, (dppe)(CO)(3)Mn-C(O)OCH3, 1, in dichloromethane saturated with water converts it to the bridging carbonato complex, (dppe)(CO)(3)Mn-OC(O)O-Mn(CO)(3)(dppe), 2. This multi-step con vers ion involves the in-situ transformation of a Mn-C bonded complex to a Mn-O bonded one. When 2 is stirred with HCl, it is converted quantitatively to the covalent chloride (dppe)(CO)(3)Mn-Cl, 11, with evolution of carbon dioxide. Similar HCl treatment of the manganese carboxylate 1 gives three compounds: the same covalent chloride, 11; the ionic chloride, [(dppe)(CO)(4)Mn]Cl-+(-), 12, and the hydride, (dppe)(CO)(3)Mn-H, 5. Reasonable schemes for these conversions are suggested. Heating the ionic chloride complex to its melting point converts it to the covalent chloride complex; the same transformation is accomplished by refluxing the ionic chloride in acetonitrile. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00486-5