| 181024-00-0

• CAS: 181024-00-0
• 化学式: C₁₄H₁₈Cl₂O₂Pt₂
• 分子量: 679.362
• InChiKey: YDYRNLZQBJFQLC-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  氘代乙腈 、 以 氘代乙腈 为溶剂， 生成
  参考文献：
  名称：

  Platinum(II)-Catalyzed Isomerization of Alkoxycyclopropanes to Alkylated Ketones

  摘要：

  Conversion of alkoxycyclopropanes to 2-methyl Ketones has been accomplished using catalytic platinum. Mechanistic studies revealed that the conversion involves platinum insertion into the cyclopropane followed by rearrangement to produce the methyl ketone.

  DOI：

  10.1021/om960157t
• 作为产物：
  描述：

  Zeise's dimer 、 1-ethoxybicyclo[4.1.0]hept-3-ene 以 乙醚 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Platinum(II)-Catalyzed Isomerization of Alkoxycyclopropanes to Alkylated Ketones

  摘要：

  Conversion of alkoxycyclopropanes to 2-methyl Ketones has been accomplished using catalytic platinum. Mechanistic studies revealed that the conversion involves platinum insertion into the cyclopropane followed by rearrangement to produce the methyl ketone.

  DOI：

  10.1021/om960157t