[((2,2'-bipyridine)(6-chloro-2-pyridonate)2(copper)(II))2] | 154790-63-3

• 英文名称: [((2,2'-bipyridine)(6-chloro-2-pyridonate)2(copper)(II))2]
• CAS: 154790-63-3
• 化学式: C₄₀H₂₈Cl₄Cu₂N₈O₄
• 分子量: 953.618
• InChiKey: PBHXMGKBQUBEKV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [((2,2'-bipyridine)(6-chloro-2-pyridonate)2(copper)(II))2] 、 copper hydroxide 以 二氯甲烷 为溶剂， 以14%的产率得到[(2,2'-bipyridine)(6-chloro-2-pyridonate)2(water)(copper)(II)]
  参考文献：
  名称：

  Novel monomeric and dimeric copper(II) pyridone complexes containing the 2,2′-bipyridyl ligand

  摘要：

  The complexes [{Cu(chp)2(bipy)}2] 1 and [Cu(mhp)2(bipy)] 2 have been prepared (chp = 6-chloro-2-pyridonate, mhp = 6-methyl-2-pyridonate, bipy = 2,2' = bipyridine). Although both are monomeric in solution, 1 is dimeric in the solid state whereas 2 retains its monomeric structure. In the presence of water, 1 reacts to give a monomeric complex, [Cu(chp)2(bipy)(H2O)] 3 which exhibits intramolecular hydrogen bonding. Reaction of 1 with Cu(NO3)2.3H2O leads to partial substitution of the pyridone ligands, forming a second dimeric material, [Cu2(chp)2(bipy)2(H2O)][NO3]2 4. The crystal structures of 1-4 have been determined.

  DOI：

  10.1039/dt9940002005
• 作为产物：
  描述：

  在 2,2'-bipyridyl 作用下， 以 二氯甲烷 为溶剂， 以92%的产率得到[((2,2'-bipyridine)(6-chloro-2-pyridonate)2(copper)(II))2]
  参考文献：
  名称：

  Novel monomeric and dimeric copper(II) pyridone complexes containing the 2,2′-bipyridyl ligand

  摘要：

  The complexes [{Cu(chp)2(bipy)}2] 1 and [Cu(mhp)2(bipy)] 2 have been prepared (chp = 6-chloro-2-pyridonate, mhp = 6-methyl-2-pyridonate, bipy = 2,2' = bipyridine). Although both are monomeric in solution, 1 is dimeric in the solid state whereas 2 retains its monomeric structure. In the presence of water, 1 reacts to give a monomeric complex, [Cu(chp)2(bipy)(H2O)] 3 which exhibits intramolecular hydrogen bonding. Reaction of 1 with Cu(NO3)2.3H2O leads to partial substitution of the pyridone ligands, forming a second dimeric material, [Cu2(chp)2(bipy)2(H2O)][NO3]2 4. The crystal structures of 1-4 have been determined.

  DOI：

  10.1039/dt9940002005