| 211807-86-2

• CAS: 211807-86-2
• 化学式: C₄₆H₅₈Cl₂N₆Rh₂Ru₂
• 分子量: 1173.86
• InChiKey: NZIZQLPEUOISSY-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Stepwise Assembly of [(C5H5)4(C5Me5)4Co4Rh4(CN)12]4+, an “Organometallic Box”

  摘要：

  A volume of 132 Å3 is enclosed by the title compound 1, which thus offers plenty of room for potential guest molecules. The synthesis from 2 [{Cp*RhCl2 }2 ] and 4 [CpCo(CN)3 ]- begins with the construction of a "molecular square" whose corners are alternately occupied by Co and Rh centers. Two squares react with one another to give a "molecular box" without cleavage of any M-C bonds. Cp=C5 H5 , Cp*=C5 Me5 .

  DOI：

  10.1002/(sici)1521-3773(19980703)37:12<1694::aid-anie1694>3.0.co;2-0