[Cu4Br4(4-amino-3,5-dimethyl-1,2,4-triazole)4] | 1297319-90-4

• 英文名称: [Cu4Br4(4-amino-3,5-dimethyl-1,2,4-triazole)4]
• 英文别名: [Cu4Br4(admtz)4]
• CAS: 1297319-90-4
• 化学式: C₁₆H₃₂Br₄Cu₄N₁₆
• 分子量: 1022.34
• InChiKey: JGUUIXMGWBURSG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-氨基-3,5-二甲基-1,2,4-三唑 、 copper(I) bromide 在 KBr 作用下， 以 水 为溶剂， 以53%的产率得到[Cu4Br4(4-amino-3,5-dimethyl-1,2,4-triazole)4]
  参考文献：
  名称：

  Syntheses, crystal structures and luminescent properties of copper(I)-halide complexes constructed by 4-amino-3,5-dimethyl-1,2,4-triazole

  摘要：

  A series of copper(I)-halide complexes with 4-amino-3,5-dimethyl-1,2,4-triazole (admtz) as bridging ligands, namely, [Cu2Cl2(admtz)(2)] (1), [Cu2Br2(admtz)(2)] (2), [Cu4Br4(admtz)(4)] (3) and [Cu2I2(admtz)(2)](n) (4), have been synthesized under hydrothermal conditions. X-ray single-crystal diffraction reveals that 1 and 2 show discrete dimeric structures, in which hydrogen bonds link the dimers into 2D networks. Complex 3 adopts a discrete tetrameric structure, which is further connected into a 3D network by C-H center dot center dot center dot Br non-classical hydrogen bonds. Complex 4 displays a 1D chain that is be further extended into a 2D framework by N-H center dot center dot center dot I weak interactions. The photoluminescent and luminescence lifetime measurements reveal that 1, 2 and 4 exhibit extensive green-blue phosphorescences in the solid state at room temperature, whereas 3 shows much weaker fluorescent emissions and shorter luminescence lifetimes. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.090