| 1569271-28-8

• CAS: 1569271-28-8
• 化学式: C₁₇H₂₀Cl₂NRh
• 分子量: 412.164
• InChiKey: RTSUVKLHQMXAEH-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  2-乙炔基吡啶 、 dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 以 二氯甲烷 为溶剂， 反应 3.0h， 以98%的产率得到
  参考文献：
  名称：

  N-Metallacycles from [Cp*MX₂]₂ and Alkynylpyridines: Synthesis, Reaction Pathway, and Aromaticity

  摘要：

  The reaction of [Cp*MX2](2) (M = Rh or Ir, X = Cl, Br, or I) with alkynylpyridines afforded halogen-substituted N-metallacyclic complexes. The reaction pathway has been examined through deuterium labeling and other experiments and computational studies and is proposed to proceed via halide dissociation followed by attack at the alkyne. These N-metallacycles exhibit aromaticity and undergo Sonogashira coupling reactions.

  DOI：

  10.1021/om401154c