tribromo(12,13:26,27-dibenzo-1,4,7,10,15,18,21,24-octaazacyclooctacosane-1,10,15,24-tetraenedizinc(II)) bromide | 385843-21-0

• 英文名称: tribromo(12,13:26,27-dibenzo-1,4,7,10,15,18,21,24-octaazacyclooctacosane-1,10,15,24-tetraenedizinc(II)) bromide
• CAS: 385843-21-0
• 化学式: Br*C₂₈H₄₀Br₃N₈Zn₂
• 分子量: 939.075
• InChiKey: AIKFIUJGGYJLPS-IADGGMIYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三乙烯四胺 、 zinc(II) bromide dihydrate 、 邻苯二甲醛 以 甲醇 为溶剂， 以40%的产率得到tribromo(12,13:26,27-dibenzo-1,4,7,10,15,18,21,24-octaazacyclooctacosane-1,10,15,24-tetraenedizinc(II)) bromide
  参考文献：
  名称：

  BINUCLEAR N₈ 28-MEMBERED MACROCYCLIC TRANSITION METAL COMPLEXES: SYNTHESIS AND CHARACTERIZATION

  摘要：

  A novel family of tetraimineoctaaza macrocyclic complexes [M2LX3]X, (M = Co(II), Ni(II), Cu(II) and Zn(II); X = Cl or Br) has been prepared by the condensation reaction of triethylenetetramine with phthalaldehyde in methanol in the presence of metal ions as templates. The complexes have been characterized on the bases of elemental analyses, 1R, H-1 NMR and UV-Vis spectroscopic studies, as well as conductivity and magnetic susceptibility data. The coordination geometry around the metal ions is octahedral in which a single halogen bridges the two metal ions.

  DOI：

  10.1081/sim-100107208