(ruthenium(II)(CO)[C6H4(O)CHNNHC3HNSC4H5(CH3)(C6H2(CH3)3)]2(piperidine) | 872678-50-7

• 英文名称: (ruthenium(II)(CO)[C6H4(O)CHNNHC3HNSC4H5(CH3)(C6H2(CH3)3)]2(piperidine)
• CAS: 872678-50-7
• 化学式: C₅₄H₆₃N₇O₃RuS₂
• 分子量: 1023.34
• InChiKey: YRPHNWDPUMIBAN-ZEYONNNGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [RuHCl(CO)(triphenylphosphine)2(piperidine)] 、 2-((2-(5-(3-mesityl-3-methylcyclobutyl)thiazol-2-yl)hydrazineylidene)methyl)phenol 以 苯 为溶剂， 生成 (ruthenium(II)(CO)[C6H4(O)CHNNHC3HNSC4H5(CH3)(C6H2(CH3)3)]2(piperidine)
  参考文献：
  名称：

  Ruthenium(II) Complexes Derived from Substituted Cyclobutane and Substituted Thiazole Schiff Base Ligands: Synthetic, Spectral, Catalytic and Antimicrobial Studies

  摘要：

  Ruthenium(II) complexes of the type [Ru(CO)(L)(2)( B)] (L = novel bidentate Schiff base ligand; B = PPh3, pyridine (py), piperidine (pip), morpholine (morph) or AsPh3) have been prepared by reacting [RuHCl(CO)(PPh3)(2)(B)] (B = PPh3, py, pip or morph) or [RuHCl(CO)(AsPh3)(3)] with two novel bidentate Schiff base ligands derived from 4-(1-methyl-1- mesitylcyclobutane-3- yl)-2-aminothiazole in 1 : 2 molar ratio in benzene. Complexes have been characterized by analytical, spectroscopic (IR, UV, H-1, C-13- and P-31 NMR) and magnetic data. An octahedral structure has been tentatively proposed for all the new complexes. The thermal properties of the ligands and their complexes have been studied by TGA. The new complexes have been used as catalyst in aryl-aryl coupling and also subjected to antibacterial and antifungal activity studies.

  DOI：

  10.1081/sim-200067062