{Fe(II)(FPSC)Cl2} | 128844-59-7

• 英文名称: {Fe(II)(FPSC)Cl2}
• 英文别名: chloro (1-((E)-2-pyridinylmethylidene)semicarbazone)iron(II) chloride
• CAS: 128844-59-7；1355153-45-5
• 化学式: C₇H₈ClFeN₄O*Cl
• 分子量: 290.92
• InChiKey: BDMCNQHRQFWLRK-RWWJYAHQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-pyridylcarbaldehyde (E)-semicarbazone 、 iron(II) chloride 在 triethylorthoformate 作用下， 以 乙醇 为溶剂， 以53%的产率得到{Fe(II)(FPSC)Cl2}
  参考文献：
  名称：

  Synthesis, characterization and chemical properties of 1-((E)-2-pyridinylmethylidene)semicarbazone manganese(II) and iron(II) complexes

  摘要：

  Manganese(II) perchlorate and iron(II) chloride react with 2-formylpyridine semicarbazone (HCSpy) in boiling ethanol to produce [Mn-II(HSCpy)(2)](ClO4)(2)center dot C2H5OH and [(FeCl)-Cl-II(HSCpy)]Cl. The distorted octahedral manganese complex crystallizes in the triclinic system with space group P(-1). The ligand HSCpy is tridentate and is coordinated through two nitrogen and one oxygen atoms. Comparison of the bond distances with analogous transition metal complexes that have the same geometry revealed longer bonds for the manganese derivative, an outcome that correlates well with the radius of the metal ions. The iron(II) ion is tetracoordinated to one semicarbazone and one chloride. Mass spectrometry, conductivity measurements, Mossbauer, UV-VIS, FTIR and elemental analysis were all in accordance with the proposed composition and the plausible geometry of [FeCI(HSCpy)]CI. Mass spectrometry unequivocally detected the presence of the [FeCI(HSCpy)](+) ion with a m/z of 254.97 and intensity of 2 x 10(5). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2011.11.016