diphenyl[(N,N-trimethylammoniomethylferrocenyl)iodide]stibine | 911852-62-5

• 英文名称: diphenyl[(N,N-trimethylammoniomethylferrocenyl)iodide]stibine
• CAS: 911852-62-5
• 化学式: C₂H₆O*C₂₆H₂₉FeNSb*I
• 分子量: 706.094
• InChiKey: XOVRFXYCNYPJCJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙醇 、 rac-diphenyl(N,N-dimethylaminomethylferrocenyl)stibine 、 碘甲烷 以 二氯甲烷 为溶剂， 以93%的产率得到diphenyl[(N,N-trimethylammoniomethylferrocenyl)iodide]stibine
  参考文献：
  名称：

  First ferrocenylstibines and their molecular structures

  摘要：

  Stibines Ph(2)SbFc containing the pendant arm [2-(Me2NCHR)] [where R = H(1) or Me(2)] on ferrocenyl ring were synthesized, and reaction of (1) with CH3I was carried out to obtain the monoammonium salt {[2-(Me3N+CH2)Fc]) SbPh2[I](-). All new stibines have been characterized by various physicochernical techniques. The structures of all these 1,2-disubstituted ferrocenylstibines were determined by X-ray diffraction analyses. This is the first report on the stibines containing disubstituted ferrocenyl group and it is worth mentioning that even monosubstituted ferrocenylstibines are virtually unknown. Heterobimetallic stibine (1) does not show intramolecular Sb-N interactions while the stibine (2) is stabilized by intramolecular Sb-N interactions. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.09.029