Zn(diphenyldipyrazolylmethane)(NO3)Cl | 1165718-01-3

• 英文名称: Zn(diphenyldipyrazolylmethane)(NO3)Cl
• CAS: 1165718-01-3
• 化学式: C₁₉H₁₆ClN₅O₃Zn
• 分子量: 463.211
• InChiKey: DRRHDXLVNAKWRM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 二氯甲烷 、 diphenyldipyrazolylmethane 以 乙醇 、 二氯甲烷 为溶剂， 以76%的产率得到Zn(diphenyldipyrazolylmethane)(NO3)Cl
  参考文献：
  名称：

  Synthesis and characterization of a series of diphenyldipyrazolylmethane complexes with zinc(II)

  摘要：

  The zinc(II) coordination chemistry of a series of diphenyldipyrazolylmethane ligands was explored using H-1 NMR and single crystal X-ray diffraction. Unsubstituted diphenyldipyrazolylmethane (dpdpm), diphenylbis(3-methylpyrazolyl) methane (dpdp'm), and diphenylbis(3,5-dimethylpyrazolyl) methane (dpdp '' m) were reacted with Zn(NO3)(2) to afford Zn(dpdpm)(NO3) 2, Zn(dpdp'm)(NO3)(2) and Zn(Pz '')(2)(NO3)(2) where Pz '' = 3,5-dimethylpyrazole, respectively. All attempts to isolate Zn(dpdp '' m)(NO3)(2) with the intact dpdp '' m ligand were unsuccessful due to decomposition of the ligand. These bidentate ligands support the formation of 1:1 ligand to metal complexes and structurally model the two histidine coordination mode common in zinc proteins. Published by Elsevier B. V.

  DOI：

  10.1016/j.ica.2008.10.024