[Cu₂(μ-Br)(μ₄-Br){C₆H₅N{P(OC₆H₃(OMe-o)(C₃H₅-p))₂}₂}]₂ | 1580528-47-7

• 英文名称: [Cu₂(μ-Br)(μ₄-Br){C₆H₅N{P(OC₆H₃(OMe-o)(C₃H₅-p))₂}₂}]₂
• CAS: 1580528-47-7
• 化学式: C₉₂H₉₈Br₄Cu₄N₂O₁₆P₄
• 分子量: 2185.49
• InChiKey: PYGHQBRINFSCJS-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  C6H5N{P(OC6H3(OMe-o)(C3H5-p))2}2 、 copper(I) bromide 以 乙腈 为溶剂， 反应 4.0h， 以86%的产率得到[Cu₂(μ-Br)(μ₄-Br){C₆H₅N{P(OC₆H₃(OMe-o)(C₃H₅-p))₂}₂}]₂
  参考文献：
  名称：

  Short-Bite PNP Ligand-Supported Rare Tetranuclear [Cu₄I₄] Clusters: Structural and Photoluminescence Studies

  摘要：

  The group 11 metal complexes of two short-bite PNP ligands, C6H5N{P(OC6H3(OMe-o)(C3H5-p))(2)}(2) (1) and C6H5N{P(OC6H4C3H5-o)(2)}(2) (2), are described. Ligands 1 and 2 on treatment with copper(I) halides (CuX, X = Cl, Br, or I) yielded dimeric, tetranuclear complexes of the type [(CuX)(4){C6H5N(PR2)(2)}] (R = OC6H3(OMe-o)(C3H5-p), X = Cl (3), Br (5), 1(7); R = OC6H3(C3H5-o), X = Cl (4), Br (6), I (8)). The chloro-derivative 3 adopts the common "stair-step" geometry, whereas the bromo- and iodo-derivatives form Cu-4 square planes with two tetracoordinating mu(4)-halides capping the axial positions to give octahedral geometry with two other mu(2)-halides being in the plane. The iodo-derivative 8 with a very short Cu-Cu distance of 2.568 angstrom shows photoluminescence in the solid state.

  DOI：

  10.1021/ic500240j