[(C5Me5)IrCl2(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C5Me5)]PF6 | 573698-89-2

• 英文名称: [(C5Me5)IrCl2(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C5Me5)]PF6
• CAS: 573698-89-2
• 化学式: C₅₂H₅₉Cl₃Ir₂P₃*F₆P
• 分子量: 1412.72
• InChiKey: XTGUAVIAILVBBV-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 bis(diphenylphosphinomethyl)phenylphosphine 以 not given 为溶剂， 生成 [(C5Me5)IrCl2(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C5Me5)]PF6 、 [(C5Me5)IrCl2(bis(diphenylphosphinomethyl)phenylphosphine)IrCl(C5Me5)]PF6
  参考文献：
  名称：

  Stereochemistry of mono- and dinuclear complexes of rhodium, iridium and ruthenium bearing bis(diphenylphosphinomethyl)phenylphosphine

  摘要：

  Reaction Of [CP*MCl2](2) (1a: M = Rh and 1b: M = Ir) or [(C6Me6)RuCl2](2) (1c) with bis(diphenylphosphinomethyl)phenylphosphine (dpmp) in the presence of KPF6 generated mono- or dinuclear complexes [Cp*RhCl(dpmp)](PF6) (2a), [(C6Me6)RuCl(dpmp)](PF6) (5c), [CP*MCl2(dpmp)MClCp*](PF6) (3a: M = Rh and 4b: M = Ir) or [(C6Me6)RUCl2(dpmp)RUCl(C6Me6)](PF6) (6c), depending on reaction conditions. These complexes have two chiral centers and the diastereomers were separated and characterized by spectrometry and X-ray analyses. A diastereomer 2a(A) was treated with AuCl(C4H8S), generating a heterotetranuclear complex [{Cp*RhCl2(dpmp)Au}(2)](PF6)(2) (7a), whereas similar reactions of 5c gave dinuclear complex [(C6Me6)RuCl(dpmp)AuCl](PF6) (8c(A)). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00096-2