bis[N,N'-bis(mercaptoethyl)-1,5-diazacyclooctanenickel(II)]nickel(II) tetrachloronickelate | 258496-97-8

• 英文名称: bis[N,N'-bis(mercaptoethyl)-1,5-diazacyclooctanenickel(II)]nickel(II) tetrachloronickelate
• CAS: 258496-97-8
• 化学式: C₂₀H₄₀N₄Ni₃S₄*Cl₄Ni
• 分子量: 841.4
• InChiKey: HCZKEFOALJWANL-UHFFFAOYSA-F

反应信息

• 作为产物：
  描述：

  1,5-bis(2-phenylselanylsulfanylethyl)-1,5-diazocane;dichloronickel 以 甲醇 为溶剂， 生成 、 bis[N,N'-bis(mercaptoethyl)-1,5-diazacyclooctanenickel(II)]nickel(II) tetrachloronickelate
  参考文献：
  名称：

  Nickel mediated sulfur–selenium and sulfur–sulfur bond formation

  摘要：

  Electrophilic addition of the PhSeCl to a nickel dithiolate yields S,S′-bis(phenylselenenyl-N,N′-bis(mercaptoethyl)-1,5-diazacyclooctane nickel(II) dichloride and a dimeric, intermolecular bis-disulfide which results from ligand oxidation.

  DOI：

  10.1039/a903973b