| 322727-45-7

• CAS: 322727-45-7
• 化学式: C₁₃H₂₀FeO₃Si
• 分子量: 308.233
• InChiKey: LJGPRLZTAVSWIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium dicarbonyl(cyclopentadienyl)ferrate 、 tert-butoxydimethylchlorosilane 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Reactivity of the Base-Stabilized Bis(silylene)iron Complex (η⁵-C₅H₅)Fe(CO)(η²-SiMe₂-O^tBu-SiMe₂):  Elevated Temperature Trapping of SiMe₂ by R₃EH (R = Me₃Si, E = Si, Ge) and Elimination of Me₂(O^tBu)SiSiMe₂H by n-Bu₃SnH

  摘要：

  The base-stabilized silylene complex (eta (5)-C5H5)Fe(CO)(eta (2)-SiMe2-(OBu)-Bu-t-SiMe2) is unreactive toward (Me3Si)(3)EH (E = Si, Ge) under photochemical irradiation or at room temperature. However, at 80 degreesC it reacts, presumably via the equilibrium concentration of base-free complex (eta (5)-C5H5)Fe(CO)((SiMe2OBu)-Bu-t)(=SiMe2), to transfer the silylene group and form (Me3Si)(3)ESiMe2H. Attempts to transfer the SiMe2 group to tributyltin hydride led to formation of bis(tributylstannyl)iron completes.

  DOI：

  10.1021/om000563j