| 358364-82-6

• CAS: 358364-82-6
• 化学式: C₁₉H₄₉N₃Si₄Tl₂
• 分子量: 840.726
• InChiKey: RXYBZBDGZBNAJY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  thallium chloride 、 以 1,4-二氧六环 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Aggregation of tripodal thallium(I) amides through weak Tl^I⋯Tl^Iinteractions

  摘要：

  Metal exchange between the lithium amide MeSi[SiMe(2)N-(Li)Bu(t)](3) and TICl yields the corresponding thallium amide MeSi[SiMe(2)N(Tl)Bu(t)](3) 1 which aggregates in the solid through weak attractive TI TI interactions to form infinite molecular chains; competing redox chemistry leads to the dimetallated species HC[SiMe(2)N(Tl)Bu(t)](2)[SiMe(2)NHBu(t)] 2 in the analogous metal-exchange process involving the trisilylmethane derivative.

  DOI：

  10.1039/cc9960002515