[Co(2,2':6',2''-terpyridine)Cl(H2O)]Cl*H2O | 691869-62-2

• 英文名称: [Co(2,2':6',2''-terpyridine)Cl(H2O)]Cl*H2O
• 英文别名: [Co(terpy)Cl(H2O)]Cl*H2O
• CAS: 691869-62-2
• 化学式: C₁₅H₁₃ClCoN₃O*Cl*H₂O
• 分子量: 399.202
• InChiKey: DBEOJGNSIZQNAQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Co(2,2':6',2''-terpyridine)Cl(H2O)]Cl*H2O 、 水 、 二硫代乙酰胺 以 甲醇 为溶剂， 生成 [Co(2,2':6',2''-terpyridine)(dithiooxamide)2]Cl2*4H2O
  参考文献：
  名称：

  Investigations of Co(II), Ni(II) and Cu(II) (2,2´:6´,2"2"-Terpyridine) Complexes With Sulfur Donor Ligands

  摘要：

  The 'complexes as metal' strategy has been used to prepare new mixed ligand complexes containing Co(II), Ni(II) and Cu(II) terpyridine (terpy) with dithiooxamide (dto) and thiosemicarbazide (tsc). Characterization of the complexes has been accomplished by elemental analysis, molar conductance, thermal analysis, as well as electronic and IR spectral measurements. It is deduced that the coordination mode of the terpyridine is changed from tridentate in the binary complex to bidentate in the ternary one where the uncoordinated pyridine exists in the protonated form. The dto and tsc act as neutral bidentate ligands coordinating through either sulfur or sulfur and nitrogen atoms respectively, forming chelate ring systems.

  DOI：

  10.1023/b:jtan.0000011012.07721.e1
• 作为产物：
  描述：

  α,α,α-三联吡啶 、 cobalt(II) chloride hexahydrate 、 水 以 甲醇 为溶剂， 生成 [Co(2,2':6',2''-terpyridine)Cl(H2O)]Cl*H2O
  参考文献：
  名称：

  Investigations of Co(II), Ni(II) and Cu(II) (2,2´:6´,2"2"-Terpyridine) Complexes With Sulfur Donor Ligands

  摘要：

  The 'complexes as metal' strategy has been used to prepare new mixed ligand complexes containing Co(II), Ni(II) and Cu(II) terpyridine (terpy) with dithiooxamide (dto) and thiosemicarbazide (tsc). Characterization of the complexes has been accomplished by elemental analysis, molar conductance, thermal analysis, as well as electronic and IR spectral measurements. It is deduced that the coordination mode of the terpyridine is changed from tridentate in the binary complex to bidentate in the ternary one where the uncoordinated pyridine exists in the protonated form. The dto and tsc act as neutral bidentate ligands coordinating through either sulfur or sulfur and nitrogen atoms respectively, forming chelate ring systems.

  DOI：

  10.1023/b:jtan.0000011012.07721.e1