[Pd(N,N'-diphenyl-2-iminoisoindoline)Cl(triphenylphosphine)] | 1158090-24-4

• 英文名称: [Pd(N,N'-diphenyl-2-iminoisoindoline)Cl(triphenylphosphine)]
• CAS: 1158090-24-4
• 化学式: C₃₈H₃₀ClN₂PPd
• 分子量: 687.516
• InChiKey: HXMWGHFQESAYNC-BFUOAJNWSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(μ-acetato)(1-phenylimino-2-phenylisoindoline)dipalladium(II) 、 三苯基膦 、 lithium chloride 以 二氯甲烷 为溶剂， 以84%的产率得到[Pd(N,N'-diphenyl-2-iminoisoindoline)Cl(triphenylphosphine)]
  参考文献：
  名称：

  Mononuclear palladacycles of N,N′-diaryl-2-iminoisoindolines

  摘要：

  Reaction of acetato-bridged dinuclear palladacycles, [Pd(iminoisoindoline)(mu-OAc)](2), with stoichiometric amounts of PR3 (where R = Ph or Cy) resulted in formation of the corresponding mononuclear phosphine-ligated, six-membered palladacycles with the general formula [Pd(iminoisoindoline)(OAc) PR3]. The analogous chloride complexes were synthesized by reaction of [Pd(iminoisoindoline)(mu-OAc)](2) with LiCl in acetone followed by addition of phosphine to afford the monomeric derivatives [Pd(iminoisoindoline)(Cl)PR3]. Representative crystal structures of both types of mononuclear palladacycles confirmed the mononuclear nature of the complexes and showed a trans-arrangement of the phosphine ligand to the heterocyclic imine-nitrogen of the palladacycles. (c) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.12.055