1-ferrocenyl-2-((2,6-bis(pyrazolyl)pyridyl)ethylene) | 938063-54-8

• 英文名称: 1-ferrocenyl-2-((2,6-bis(pyrazolyl)pyridyl)ethylene)
• CAS: 938063-54-8
• 化学式: C₂₃H₁₉FeN₅
• 分子量: 421.284
• InChiKey: CKENRKNZFGKYDM-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  iron(II) tetrafluoroborate hexahydrate 、 乙醚 、 1-ferrocenyl-2-((2,6-bis(pyrazolyl)pyridyl)ethylene) 以 甲醇 为溶剂， 以38%的产率得到[Fe(1-ferrocenyl-2-((2,6-bis(pyrazol-1-yl)pyridyl)ethylene)2](BF4)2*2OEt2
  参考文献：
  名称：

  Magnetic Bistability and Single-Crystal-to-Single-Crystal Transformation Induced by Guest Desorption

  摘要：

  An iron(II) complex with ferrocenyl groups, [Fe(dppFc)(2)](BF4)(2)center dot 2Et(2)O (1 center dot 2Et(2)O, dppFc = 1-ferrocenyl-2-{(2,6-bis(pyrazolyl)pyridyl}ethylene), was prepared. X-ray crystallographic analyses revealed that 1 center dot 2Et(2)O underwent a single-crystal-to-single-crystal transformation with the release of crystal solvent molecules. In magnetic susceptibility measurements, a reversible conversion between paramagnetism and spin-crossover induced by solvent molecules was observed.

  DOI：

  10.1021/ja069120i