uranium monoxide | 12035-97-1

• 英文名称: uranium monoxide
• CAS: 12035-97-1
• 化学式: OU
• 分子量: 254.028
• InChiKey: ARCUKJFDARVQKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.12
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  uranium monoxide 、 salicylidene-3-imino-3-(o-formyl) phenoxy propionic acid hydrazide 以 乙醇 、 水 为溶剂， 以78%的产率得到UO2(salicylidene-3-imino-3-(o-formyl) phenoxy propionic acid hydrazido)2*5H2O
  参考文献：
  名称：

  El-Shazly, R. M.; El-Asmy, A. A.; El-Schekeil, A., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1991, vol. 21, p. 385 - 400

  摘要：

  DOI：
• 作为产物：
  描述：

  uranyl 在 三苯基膦 作用下， 以 further solvent(s) 为溶剂， 生成 uranium monoxide
  参考文献：
  名称：

  Sidhu, M S; Chahat, Paramjit; Singh, R J, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1993, vol. 32, # 6, p. 517 - 520

  摘要：

  DOI：

文献信息

• Crossed molecular beams studies of the reactions of uranium with selected oxidizers
  作者：Neil C. Lang、Richard C. Stern、Michael G. Finley

  DOI：10.1016/0009-2614(80)85067-6

  日期：1980.1

  Angular distributions of UO produced from the reaction of U with O2, NO, NO2, and SO2 were measured using crossed molecular beams. Total cross sections for these four reactions as well as for U + N3O and U + CO2 were estimated from product scattering signals. The cross sections range from 33 Å2 for U + NO to 1 Å2 for U + CO2, and U + N2O.

  使用交叉分子束测量由U与O 2，NO，NO 2和SO 2反应产生的UO的角分布。从产物散射信号估计这四个反应以及U + N 3 O和U + CO 2的总横截面。的横截面范围从33埃2为U + NO：1的2为U + CO 2，和U + N 2 O.
• Matrix infrared spectra of the products of uranium-atom reactions with carbon monoxide and carbon dioxide
  作者：Thomas J. Tague、Lester Andrews、Rodney D. Hunt

  DOI：10.1021/j100144a004

  日期：1993.10

  Uranium atoms from pulsed Nd:YAG laser ablation of a uranium metal target were codeposited with carbon monoxide and carbon dioxide in excess argon at 10 K. Infrared spectra following the U + CO reaction revealed strong new absorption bands at 804.4 and 852.6 cm-1, which are assigned to the CUO product on the basis of isotopic shifts, FG matrix calculations, and ab initio pseudopotential calculations. An absorption at 2027.5 cm-1 is attributed to the asymmetric secondary reaction product CU(O)CO. In both the U + CO and U + CO2 reactions, bands at 870.9 and 1963.8 cm-1 were observed and assigned to the association product Of UO2 and CO. Lastly, in the U + CO2 experiments, new absorption band pairs were observed at 804.4 and 1799.6 cm-1 and at 801.5 and 2011.7 cm-1. The former pair was almost destroyed on annealing and is assigned to the OUCO insertion product. The latter pair is attributed to an OCU(O)CO species. The direct reaction of U atoms with CO and CO2 requires an activation energy, which is provided by hyperthermal U atoms from pulsed laser evaporation.
• HARADA, ISAO;YODA, YUKIHIRO;IWANAGA, NARUYUKI;NISHITSUJI, TOSHIHIKO;KIKKA+
  作者：HARADA, ISAO、YODA, YUKIHIRO、IWANAGA, NARUYUKI、NISHITSUJI, TOSHIHIKO、KIKKA+

  DOI：——

  日期：——