| 1427272-91-0

• CAS: 1427272-91-0
• 化学式: C₃₂H₂₅CuF₁₂N₃*F₆Sb
• 分子量: 978.838
• InChiKey: FNPDBIFJUVDFBN-ALGMXBCWSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  silver hexafluoroantimonate 、 乙烯 、 cis,cis-1,3,5-tris(2-fluoro-6-(trifluoromethyl)benzylideneamino)cyclohexane 、 copper(I) bromide 以 二氯甲烷 为溶剂， 20.0 ℃ 、1.0 MPa 条件下， 反应 8.0h， 以80%的产率得到
  参考文献：
  名称：

  New Cu(I)-Ethylene Complexes Based on Tridentate Imine Ligands: Synthesis and Structure

  摘要：

  A new bulky facially coordinating N-3-donor tach-based ligand (tach: cis,cis-1,3,5-triaminocyclohexane) [1: cis,cis-1,3,5-tris(2-fluoro-6-(trifluoromethyl)-benzylideneamino)cyclohexane] has been obtained from the condensation of tach with 3 equiv of the appropriate benzaldehyde. Reaction of 1 with [Cu(NCMe)(4)][PF6] gave the complex [(1)Cu(NCMe)][PF6]. Displacement of the acetonitrile ligand is possible with CO and C2H4 (3-5 bar). Cu(I)-ethylene complexes of ligands 1 and 2 [2: cis,cis-1,3,5-(mesitylideneamino)cyclohexane] were prepared successfully by treatment of the ligands with CuBr and AgSbF6 in the presence of ethylene. These complexes display reversible complexation of the ethylene molecule under mild changes to pressure, suggesting possible application in olefin separation and extraction.

  DOI：

  10.1021/ic302325u