3,9-Bis-dodecyloxy-2,4,8,10-tetraoxa-3,9-diphospha-spiro[5.5]undecane | 3774-11-6

• 英文名称: 3,9-Bis-dodecyloxy-2,4,8,10-tetraoxa-3,9-diphospha-spiro[5.5]undecane
• 英文别名: 3,9-Didodecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane
• CAS: 3774-11-6
• 化学式: C₂₉H₅₈O₆P₂
• 分子量: 564.723
• InChiKey: URIPSTIXNBHUME-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.8
• 重原子数：
  37
• 可旋转键数：
  24
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• Polyvinyl halide resin compositions containing 1,3 Dicarbonyl compounds
  申请人：PHOENIX CHEMICAL CORPORATION

  公开号：EP0040286A2

  公开（公告）日：1981-11-25

  1,3-Dicarbonyl compounds are provided having the formula: wherein: R1 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and R2 is selected from the group consisting of hydrocarbon having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; R3 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; as well as metal and organotin enolate salts thereof. The compounds are effective in enhancing the resistance to deterioration by heat and light of polyvinyl halide resins.

  1,3-二羰基化合物的化学式如下 其中 R1 选自氢、具有 1 至约 18 个碳原子的烃基和被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基的基团取代的此类基团组成的组，和 R2 选自具有 1 至约 18 个碳原子的烃以及被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基的基团取代的烃所组成的组； R3 选自由氢、具有 1 至约 18 个碳原子的烃基以及被 1 个或多个选自由卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基组成的基团取代的烃基所组成的组； 以及它们的金属盐和有机锡烯酸盐。 这些化合物可有效提高聚乙烯卤化树脂的耐热和耐光劣化性能。
• Homogeneous storage-stable liquid barium-cadmium-triphosphite stabilizer systems for polyvinyl chloride resins
  申请人：Argus Chemical Corporation

  公开号：EP0047894A2

  公开（公告）日：1982-03-24

  Homogeneous storage-stable liquid stabilizer systems for polyvinyl chloride resins are provided which are substantially soivent-free and have a low viscosity and a minimum flash point of 96°C, containing, as the essential ingredients, a liquid barium carbonate-barium alkyl phenate; a cadmium salt of a branched chain aliphatic carboxylic acid having from about five to about thirteen carbon atoms, and/or of an aromatic carboxylic acid having from about seven to about eleven carbon atoms, and/or of an unsaturated aliphatic carboxylic acid having from about twelve to about twenty-two carbons; and a liquid organic triphosphite in an amount to form a homogeneous storage-stable liquid; the total weight percent of barium and cadmium in the stabilizer system being at least 13%, and the ratio of the weight percent of cadmium to the weight percent of barium being within the range from about 0.5:1 to about 1.5:1; optionally together with any one or more of a soluble zinc salt of a carboxylic acid, a soluble phenolic antioxidant, a liquid organic acid phosphite, and a soluble carboxylic acid.

  本发明提供了用于聚氯乙烯树脂的贮存稳定的均相液体稳定剂体系，该体系基本上不含溶剂，具有低粘度，最低闪点为96°C，其基本成分包括液体碳酸钡-烷基酚钡；具有约 5 至约 13 个碳原子的支链脂肪族羧酸的镉盐，和/或具有约 7 至约 11 个碳原子的芳香族羧酸的镉盐，和/或具有约 12 至约 22 个碳原子的不饱和脂肪族羧酸的镉盐；和液态有机三亚磷酸，其用量可形成均匀的储存稳定液体；稳定剂体系中钡和镉的总重量百分比至少为 13%，镉的重量百分比与钡的重量百分比之比范围在约 0.5:1至约1.5:1的范围内；可选择与羧酸的可溶性锌盐、可溶性酚类抗氧化剂、液态有机亚磷酸酯和可溶性羧酸中的任意一种或多种一起使用。
• Stabilized Polyvinylhalide resin
  申请人：PHOENIX CHEMICAL CORPORATION

  公开号：EP0046161A2

  公开（公告）日：1982-02-24

  1,3-Dicarbonyl compounds are provided having the formula: wherein: R1 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COORl, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and R2 is selected from the group consisting of hydrocarbon having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; one R1 and R2 may be linked together as an alkylene group to form a cyclic or ring structure; n is number from 1 to 3; and Z is a polyvalent linking radical selected from the group consisting of a direct linkage between the groups; polyvalent hydrocarbon R3; wherein: R3 is a polyvalent hydrocarbon group having from one to about eighteen carbon atoms; R4 and Rs are selected from the group consisting of hydrogen and hydrocarbon groups having from one to about eighteen carbon atoms; and R4 and R5 may be linked together as an alkylene to form a cyclic or ring structure; X is -O- od -S-; m is 0 or 1; and R6 is selected from the group consisting of hydrogen, hydrocarbon having from one to about eighteen carbon atoms, and -R3-; as well as metal and organotin enolate salts thereof. The compounds are effective in enhancing the resistance to deterioration by heat and light of polyvinyl halide resins.

  1,3-二羰基化合物的化学式如下 其中 R1 选自氢、具有 1 至约 18 个碳原子的烃基和被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COORl、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基的基团取代的此类基团组成的组，以及 R2 选自具有 1 至约 18 个碳原子的烃组成的组，以及被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基组成的组取代的此类基团； 一个 R1 和 R2 可作为亚烷基连接在一起，形成环状或环状结构； n 为 1 至 3；以及 Z 是多价连接基，选自由基团之间的直接连接、多价烃基 R3 组成的组； 其中 R3 是具有 1 至约 18 个碳原子的多价烃基； R4 和 Rs 选自氢和具有 1 至约 18 个碳原子的烃基；R4 和 R5 可作为亚烷基连接在一起，形成环状或环状结构； X 是-O- od -S- ； m 是 0 或 1；以及 R6选自由氢、具有一至十八个碳原子的烃和-R3-组成的组，以及它们的金属盐和有机锡烯醇盐。 这些化合物可有效提高聚乙烯卤化树脂的耐热和耐光劣化性能。
• Copolymer light stabilizers having at least one 2,2,6,6-tetraalkyl piperidyl group and synthetic resin compositions containing the same
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0069871A2

  公开（公告）日：1983-01-19

  Copolymer light stabilizers are provided having at least one 2,2,6,6-tetraalkyl piperidyl group in the molecule and a molecular weight within the range from about 1000 to about 20,000, that are copolymers of a maleic or fumaric acid ester containing a 2,2,6,6-tetraalkyl piperidyl group in the alcohol group of the formula: wherein R2 is alkyl or R1; Re is lower alkyl or hydroxyalkyl; R3 is hydrogen alkaryl or alkyl, hydroxyalkyl or eopx- yalkyl; R4 is hydrogen or methyl; R5 is alkylene; Y is >CH2, >C=0, >CH-OH or R7 is alkylene; and at least one monomer selected from the group consisting of aliphatic carboxylic acid vinyl ester having from two to eight carbon atoms; alkyl vinyl ethers having from one to eighteen carbon atoms; triallyl isocyanurate; pinene; and tricyclo- (5.2.1.02.6)-decene-3; and synthetic resin compositions having improved light stability comprising per 100 parts by weight of resin from 0.001 to 5 parts by weight of the polymeric light stabilizer.

  共聚光稳定剂分子中至少有一个 2，2，6，6-四烷基哌啶基，分子量在约 1000 至约 20000 之间，是马来酸酯或富马酸酯的共聚物，其醇基中含有 2，2，6，6-四烷基哌啶基： 其中 R2 是烷基或 R1； Re是低级烷基或羟基烷基 R3 是氢烷基芳基或烷基、羟基烷基或异丙基烷基； R4 是氢或甲基 R5 是亚烷基； Y 是 >CH2、>C=0、>CH-OH 或 R7 是亚烷基； 和至少一种选自以下组别的单体：具有 2 至 8 个碳原子的脂肪族羧酸乙烯酯；具有 1 至 18 个碳原子的烷基乙烯基醚；异氰尿酸三烯丙基酯；蒎烯；和三环-(5.2.1.02.6)-癸烯-3；以及具有更高光稳定性的合成树脂组合物，其中每 100 份树脂重量包含 0.001 至 5 份聚合物光稳定剂。
• N-2-hydroxypropyl piperidines and process for preparing the same
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0058434A1

  公开（公告）日：1982-08-25

  N-2-Hydroxypropyl piperidines are provided, as well as a process for preparing these compounds, having the formula: wherein X is selected from the group consisting of wherein R is selected from the group consisting of hydrogen; alkyl; alkenyl; cycloalkyl; alkaryl; hydroxyalkyl; oxyalkyl; acyl and aroyl having from one to about eighteen carbon atoms; R2 and R3 are each selected from the group consisting of alkyl, alkenyl, cycloalkyl, alkaryl, hydroxyalkyl, oxyalkyl and haloalkyl having from one to about eighteen carbon atoms; R4, Rs and R6 each are selected from the group consisting of hydrogen, alkyl, alkenyl, cycloalkyl, alkaryl, hydroxyalkyl, oxyalkyl and haloalkyl having from one to about eighteen carbon atoms; and -CH2-O-R1; n is 1 or 2; and and Y, when n is 1, is hydroxy or and when n is 2, is oxyoxygen.

  本发明提供了 N-2-羟丙基哌啶以及制备这些化合物的工艺，其化学式为 其中 X 选自以下组成的组 其中 R 选自由 1 至约 18 个碳原子的氢、烷基、烯基、环烷基、烷芳基、羟烷基、氧烷基、酰基和芳基组成的组； R2 和 R3 分别选自由一个至约十八个碳原子的烷基、烯基、环烷基、烷芳基、羟烷基、氧烷基和卤代烷基组成的组； R4、Rs 和 R6 各选自氢、烷基、烯基、环烷基、烷芳基、羟烷基、氧烷基和卤代 烷基（具有 1 至约 18 个碳原子）组成的组；和 -CH2-O-R1; n 是 1 或 2；和 Y，当 n 是 1 时，是羟基或 当 n 为 2 时，为氧基。