| 1229662-45-6

• CAS: 1229662-45-6
• 化学式: C₈₈H₉₂Ga₂N₄
• 分子量: 1345.17
• InChiKey: PCXULTIEPOTHCM-JTAKBYLWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 acetonitrile 为溶剂， 生成 (1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene dianion)Ga-Ga(1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene dianion)
  参考文献：
  名称：

  Reversible Addition of Alkynes to Gallium Complex of Chelating Diamide Ligand

  摘要：

  Different alkynes add reversibly to the gallium complex of the dpp-Bian dianion. The reactions proceed with addition of the alkynes the Ga-N-C fragment resulting in carbon-carbon and carbon-gallium bonds. In the case of 3 and 4 a full elimination of the alkyne takes place at T < 100 degrees C, whereas with adducts 5 and 6 it occurs at heating to ca. 200 degrees C.

  DOI：

  10.1021/ja103467a
• 作为产物：
  描述：

  (1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene dianion)Ga-Ga(1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene dianion) 、 苯乙炔 以 toluene 为溶剂， 生成
  参考文献：
  名称：

  Reversible Addition of Alkynes to Gallium Complex of Chelating Diamide Ligand

  摘要：

  Different alkynes add reversibly to the gallium complex of the dpp-Bian dianion. The reactions proceed with addition of the alkynes the Ga-N-C fragment resulting in carbon-carbon and carbon-gallium bonds. In the case of 3 and 4 a full elimination of the alkyne takes place at T < 100 degrees C, whereas with adducts 5 and 6 it occurs at heating to ca. 200 degrees C.

  DOI：

  10.1021/ja103467a

文献信息

• Synthesis and structure of bischelate gallium complexes (dpp-bian)Ga(acac) and (dpp-bian)Ga(2,2´-bipy) (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene)
  作者：V. A. Dodonov、A. A. Skatova、A. V. Cherkasov、I. L. Fedushkin

  DOI：10.1007/s11172-016-1433-9

  日期：2016.5

  a transfer of electrons from the metal—metal bond to dpp-bian with the formation of the complex [(dpp-bian)Ga(acac)] (3), in which the dpp-bian ligand is a dianion. A reaction of digallane 1 with 2,2´-bipyridyl at 200 °C in toluene in a sealed tube leads to the reduction of 2,2´-bipyridyl and gives the complex [(dpp-bian)Ga(bipy)] (4), which contains two different chelate redox-active ligands. The

  digalane [(dpp-bian)Ga-Ga(dpp-bian)] (1)（dpp-bian 是 1,2-双[（2,6-二异丙基苯基）亚氨基]苊）与一当量的 I2 的反应导致化合物 1 中的 (dpp-bian)2– 氧化为 (dpp-bian)– 并生成 [(dpp-bian)Gal-GaI(dpp-bian)] (2)。在化合物 2 与两当量 (acac)Na 的反应中，不仅发生了碘离子和乙酰丙酮酸根离子的交换，而且电子从金属-金属键转移到 dpp-bian 并形成配合物。 (dpp-bian)Ga(acac)] (3)，其中 dpp-bian 配体是二价阴离子。在 200 °C 的密封管中，二镓烷 1 与 2,2'-联吡啶在甲苯中的反应导致 2,2'-联吡啶的还原，并得到复合物 [(dpp-bian)Ga(bipy)] (4 )，其中包含两种不同的螯合氧化还原活性配体。新化合物通过