| 1374875-49-6

• CAS: 1374875-49-6
• 化学式: C₁₆H₁₉ClNPdS₂*F₆P
• 分子量: 576.303
• InChiKey: FEYZZKJGJATIRW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 N-[(2-methylsulfanylphenyl)methyl]-2-phenylsulfanylethanamine 、 palladium dichloride 以 甲醇 、 乙腈 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Palladium(II) complexes of tridentate chalcogenated Schiff bases and related ligands of (S, N, S/Se/Te) type: Synthesis and structural chemistry

  摘要：

  The reactions in CH3CN between PdCl2 and Schiff base ligands, 2-MeSC6H4-CH=NCH2CH2E-C6H4-4-R (L1-L3) (E = S or Se, R = H; E = Te, R = OCH3) and their reduced derivatives 2-MeSC6H4CH2-NHCH2CH2E-C6H4-4-R (L4-L6) followed by treatment with AgPF6 or AgClO4 have resulted in complexes [PdCl(L)][ X] (1-6; L = L1-L6; X = PF6 or ClO4) which have been characterized by IR, H-1, C-13{H-1}, Se-77{H-1} and Te-125{H-1} NMR spectroscopy. Single crystal structures of complexes 1-6 reveal nearly square planar geometry around palladium in all of them (Pd-Se = 2.4045(16)-2.4065(6) angstrom; Pd-Te = 2.5052(9)-2.5307(13) angstrom). The various non-covalent interactions in the crystals result in the formation of chains, rings and caging of anions between cations. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.01.007