| 180466-76-6

• CAS: 180466-76-6
• 化学式: C₄₀H₅₇O₂P₂Rh
• 分子量: 734.744
• InChiKey: FLGJGAWOTPEWCE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  trans-[RhCl(=C=C=CPh2)(P(i)Pr3)2] 在 t-BuOK 作用下， 以 叔丁醇 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Generation of γ-functionalized alkynyl ligands by migratory insertion of an allenylidene unit into a M–OR bond

  摘要：

  The hydroxyrhodium(I) complexes 2a,b, which are prepared from the corresponding chloro derivatives 1a,b and KOBu(t), react with acetic acid and phenol at room temperature to give the new acetato and phenolate metal compounds 3a,b and 4a,b almost quantitatively; subsequent treatment of 3a,b and 4a,b with CO leads to migratory insertion of the allenylidene unit into the Rh-OR bond to yield gamma-functionalized alkynyl ligands.

  DOI：

  10.1039/cc9960001413