(η5-indenyl)(CO)2Re(C(CCC6H4-p-CH3)(C6H4-p-CF3)) | 351903-79-2

• 英文名称: (η5-indenyl)(CO)2Re(C(CCC6H4-p-CH3)(C6H4-p-CF3))
• CAS: 351903-79-2
• 化学式: C₂₈H₁₈F₃O₂Re
• 分子量: 629.652
• InChiKey: CLMLGIWVOFYTAG-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (η5-indenyl)(CO)2Re(C(C6H4-p-CH3)(CCC6H4-p-CF3)) 以 氘代甲苯 为溶剂， 生成 (η5-indenyl)(CO)2Re(C(CCC6H4-p-CH3)(C6H4-p-CF3))
  参考文献：
  名称：

  [1,3]-Metal Shifts in Rhenium Alkynyl Carbene Complexes

  摘要：

  The electron-withdrawing SO2CF3 substituent of Cp(CO)(2)Re=C(Tol)(C equivalent to CC6H4-p-SO2CF3) (1d) greatly accelerates rearrangement via a [1,3]-rhenium shift. The [1,3]-rhenium shift is proposed to proceed via an 18-electron dehydrometallacyclobutadiene intermediate formed by alkyne coordination concerted with an eta (5)-eta (3) CP ring slip.

  DOI：

  10.1021/om0103299