[Cp(*)[MeC(NPr(i))2]TaCl2]SbF6 | 250596-43-1

• 英文名称: [Cp(*)[MeC(NPr(i))2]TaCl2]SbF6
• CAS: 250596-43-1
• 化学式: C₁₈H₃₂Cl₂N₂Ta*F₆Sb
• 分子量: 764.06
• InChiKey: RWTUPAYNIRIHQE-UHFFFAOYSA-F

反应信息

• 作为产物：
  描述：

  silver hexafluoroantimonate 、 Cp(*)[MeC(NPr(i))2]TaCl3 以 二氯甲烷 为溶剂， 以64%的产率得到[Cp(*)[MeC(NPr(i))2]TaCl2]SbF6
  参考文献：
  名称：

  The Synthesis and Olefin Reactivity of Neutral and Cationic Tantalum Amidinate−Pentamethylcyclopentadienyl Complexes

  摘要：

  Cp*[MeC(NPri)(2)]TaCl3, 1, was prepared in a 60% yield by the reaction of Cp*TaCl4 with 1 equiv of Li[MeC(NPri)(2)] in THF. The structure is pseudo-octahedral with a plane of symmetry containing the amidinate ligand and bisecting the Cp*. Reaction of 1 with excess MeMgCl yielded the trimethyl derivative Cp*[MeC(NPri)(2)]TaMe3. Reaction of 1 with AgSbF6 yielded the cation [Cp*[MeC(NPri)(2)]TaCl2][SbF6]. The amidinate orientation is changed with respect to 1 such that the amidinate and the Cp* are nearly parallel. Complex 1 polymerizes ethylene upon treatment with MAO in isobutane (470 (g PE)(mmol Ta)(-1) h(-1) atm(-1)).

  DOI：

  10.1021/om990406o