| 1600530-66-2

• CAS: 1600530-66-2
• 化学式: C₂₉H₂₆F₃O₆PRuS₂
• 分子量: 723.693
• InChiKey: LFKPLBBXJCAQAQ-NTYVCIBKSA-L

反应信息

• 作为产物：
  描述：

  、 在 silver tetrafluoroborate 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以72%的产率得到
  参考文献：
  名称：

  Ruthenium(IV) Complexes for Ethylene Insertion Polymerization

  摘要：

  The synthesis, characterization, and ethylene polymerization behavior of novel Ru-IV(eta(3):eta(3)-C10H16)(OPO) (OPO = bis(arenesulfonato)phosphine) complexes is reported here. Upon activation with AlMe3-depleted methylaluminoxane (dMAO), the Ru(IV) precursors were able to produce polyethylene with activities up to 1182 h(-1) turnover frequency (TOF). The polymers were highly linear with a low degree of branching (<12 methyl branches per 1000 C) and had high molecular weights (up to M-p = 289 kg mol(-1)) with a bimodal molecular weight distribution. The polymerization activity increased with decreasing donor strength of the OPO ligand.

  DOI：

  10.1021/om5001343