[(η-C5H5)ZrCl2[(CH2)4C(η-C5H4)(η-C9H6)]ZrCl2(η-C5H5)2] | 206071-42-3

• 英文名称: [(η-C5H5)ZrCl2[(CH2)4C(η-C5H4)(η-C9H6)]ZrCl2(η-C5H5)2]
• CAS: 206071-42-3
• 化学式: C₂₉H₂₈Cl₄Zr₂
• 分子量: 700.801
• InChiKey: ABKPARDRVDPBTN-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  (η5-cyclopentadienyl)trichlorozirconium dimethoxyethane 、 以 甲苯 为溶剂， 以29%的产率得到[(η-C5H5)ZrCl2[(CH2)4C(η-C5H4)(η-C9H6)]ZrCl2(η-C5H5)2]
  参考文献：
  名称：

  Homo- and hetero-binuclear ansa-metallocenes of the group 4 transition metals as homogeneous co-catalysts for the polymerisation of ethene and propene

  摘要：

  The compounds [M{(CH2)(4)C(eta-C5H4)(2)}(eta-C5H5)Cl] (M = Zr*, Hf), [M{(CH2)(4)C(eta-C5H4)(2)}(eta-C5H5)Me] (M = Zr, Hf), [(eta-C5H5)MCl2{(CH2)(4)C(eta-C5H4)(2)}MCl2(eta-C5H5)] (M = Zr, Hf), [(eta-C5H5)ZrCl2{(CH2)(4)C(eta-C5H4)(eta-C9H6)}ZrCl2(eta-C5H5)], [(eta-C5H5)MMe2{(CH2)(4)C(eta-C5H4)(2)}MMe2(eta-C5H5)] (M = Zr, Hf), [(eta-C5H5)ZrCl2{(CH2)(4)C(eta-C5H4)(2)}HfCl2(eta-C5H5)], [(eta-C5H5)MCl2{(CH2)(4)C(eta-C5H4)(2)}Rh(eta-C8H12)] (M = Zr*, Hf), [(eta-C5H5)ZrCl2{(CH2)(4)C(eta-C5H4)(2)}TiCl3], [(eta-C5H5)ZrMe2{(CH2)(4)C(eta-C5H4)(2)}HfMe2(eta-C5H5)], [(eta-C5H5)MMe2{(CH2)(4)C(zeta-C5H4)(2)}Rh(eta-C(8)H(1)2)] (M = Zr*, Hf) have been prepared and characterised. * indicates the crystal structure has been determined. Their catalytic properties for ethene and propene polymerisation have been explored. (C) 1998 Elsevier Science B.V.

  DOI：

  10.1016/s1381-1169(97)00166-0