(Cu(N,N'-bis(2,6-Me2C6H3)nacnac))2(μ-toluene) | 1123299-03-5

• 英文名称: (Cu(N,N'-bis(2,6-Me2C6H3)nacnac))2(μ-toluene)
• 英文别名: (Cu(bis(2,6-dimethylphenyl)penta-2,4-diiminato))2(μ-toluene)
• CAS: 1123299-03-5
• 化学式: C₄₉H₅₈Cu₂N₄
• 分子量: 830.118
• InChiKey: MZBXCOKSKUPABK-NJLRLSSHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (Cu(N,N'-bis(2,6-Me2C6H3)nacnac))2(μ-toluene) 、 2,6-二甲基苯基异腈 以 甲苯 为溶剂， 以52%的产率得到Cu(N,N'-bis(2,6-Me2C6H3)nacnac)(CN(2,6-Me2C6H3))
  参考文献：
  名称：

  Syntheses and structures of bis(2,6-xylyl-nacnac) copper(I) complexes

  摘要：

  The copper(I) complexes {(bis-2,6-dimethylphenyl-penta-2,3-diiminato)Cu}(2)(mu-toluene), 3 has been prepared and its reactivity against Lewis bases and nitrous oxide investigated. Complex 3 crystallizes as a toluene-bridged dimer and forms mono- and dinuclear benzene adducts in C6D6 solution. It does not coordinate excess THF, but reacts quantitatively with 1 equiv. of acetonitrile. Reaction with 2,6-xylyl isonitrile yields (bis-2,6-dimethylphenyl-penta-2,3-diiminato) Cu(2,6-xylyl isonitrile), 5, (nu(CN) = 2123 cm (1)), which was characterized by an X-ray diffraction study. Complex 3 does not react with nitrous oxide in either C6D6 solution (5 days 50 degrees C) or in diethyl ether (13 days at ambient temperature). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.008
• 作为产物：
  描述：

  [N(2,6-dimethylphenyl)C(Me)]2CH2 、 copper (I) tert-butoxide 、 甲苯 以 甲苯 为溶剂， 以90%的产率得到(Cu(N,N'-bis(2,6-Me2C6H3)nacnac))2(μ-toluene)
  参考文献：
  名称：

  Syntheses and structures of bis(2,6-xylyl-nacnac) copper(I) complexes

  摘要：

  The copper(I) complexes {(bis-2,6-dimethylphenyl-penta-2,3-diiminato)Cu}(2)(mu-toluene), 3 has been prepared and its reactivity against Lewis bases and nitrous oxide investigated. Complex 3 crystallizes as a toluene-bridged dimer and forms mono- and dinuclear benzene adducts in C6D6 solution. It does not coordinate excess THF, but reacts quantitatively with 1 equiv. of acetonitrile. Reaction with 2,6-xylyl isonitrile yields (bis-2,6-dimethylphenyl-penta-2,3-diiminato) Cu(2,6-xylyl isonitrile), 5, (nu(CN) = 2123 cm (1)), which was characterized by an X-ray diffraction study. Complex 3 does not react with nitrous oxide in either C6D6 solution (5 days 50 degrees C) or in diethyl ether (13 days at ambient temperature). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.008