CuBr2*(1,4-dioxane)*2H2O | 1346224-22-3

• 英文名称: CuBr2*(1,4-dioxane)*2H2O
• CAS: 1346224-22-3
• 化学式: C₄H₁₂Br₂CuO₄
• 分子量: 347.491
• InChiKey: HIZVTGVCMWGRBJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4-二氧六环 、 水 、 copper(ll) bromide 以 1,4-二氧六环 、 水 为溶剂， 生成 CuBr2*(1,4-dioxane)*2H2O
  参考文献：
  名称：

  Structure of copper dihalide-1,4-dioxane-water mixed solvates

  摘要：

  Structures of three mixed solvates of copper halides: CuBr2 center dot DX center dot 2H(2)O, CuBr2 center dot 2DX center dot 2H(2)O, and CuCl2 center dot 2DX center dot 2H(2)O (DX is 1,4-dioxane) has been determined by the method of XRD on single crystals. The entry of both solvents into the first coordination sphere of the copper ion was proved. In spite of analogous composition, CuHlg(2)center dot 2DX center dot 2H(2)O solvates have different structures: the chain (Hlg = Br) and the island (Hlg = Cl) structures. The difference is caused by weakening donor power of acido ligands on passing from Br to Cl. DOI: 10.1134/S1070363211090052

  DOI：

  10.1134/s1070363211090052