[Ru(PPh3)2(CO)(N-(2'-hydroxyphenyl)-4-NO2-benzaldimine(-2H))] | 952408-91-2

• 英文名称: [Ru(PPh3)2(CO)(N-(2'-hydroxyphenyl)-4-NO2-benzaldimine(-2H))]
• CAS: 952408-91-2
• 化学式: C₅₀H₃₈N₂O₄P₂Ru
• 分子量: 893.88
• InChiKey: GKOOTENAYPARRK-XBPYKMCUSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯二羰基双(三苯基膦)钌 、 2-(4-nitro-benzylidenamino)-phenol 在 triethylamine 作用下， 以 乙二醇甲醚 为溶剂， 以78%的产率得到[Ru(PPh3)2(CO)(N-(2'-hydroxyphenyl)-4-NO2-benzaldimine(-2H))]
  参考文献：
  名称：

  Synthesis, structure and electrochemical properties of a family of organoruthenium complexes

  摘要：

  Reaction of N-(2'-hydroxyphenyl)benzaldimines (abbreviated in general as H2L-R, where R stands for the para-substituent in the benzaldehyde fragment and H stands for the dissociable hydrogen atoms) with [Ru(PPh3)(2)(CO)(2)Cl-2] affords a family of organoruthenium complexes of the type [Ru(PPh3)(2)(CO)(L-R)] where the N-(2'-hydroxyphenyl)benzaldimine ligand is coordinated to the metal center as tridentate C,N,O-donor. Structure of a representative complex has been determined by X-ray crystallography. All the [Ru(PPh3)(2)(CO)(L-R)] complexes are diamagnetic, and show characteristic H-1 NMR signals and moderately intense MLCT transitions in the visible region. Cyclic voltammetry of the [Ru(PPh3)(2)(CO)(L-R)] complexes shows a reversible Ru(II)-Ru(III) oxidation within 0.38-0.68 V versus SCE, followed by an irreversible oxidation of the coordinated benzaldimine ligand within 1.09-1.27 V versus SCE. An irreversible reduction of the coordinated benzaldimine ligand is also observed near -1.1 V versus SCE. Potential of the Ru(II)-Ru(III) oxidation is observed to be sensitive to the nature of para-substituent R. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.04.020