| 137140-13-7

• CAS: 137140-13-7
• 化学式: 0CH₂Cl₂*C₃₄H₂₃Fe₂O₈Os₃P
• 分子量: 1315.29
• InChiKey: VESCTVYDWFLLQD-YQIZFKJBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 CH₂Cl₂ 作用下， 以 正辛烷 为溶剂， 以15%的产率得到
  参考文献：
  名称：

  Iron-osmium bonding in clusters containing ferrocene fragments

  摘要：

  Pyrolysis of Os3(CO)10(PFcPh2)2 and Os3(CO)11(PFc2Ph) affords Os3(CO)8(H)2[PAr(C6H5)(eta-C5H3)Fe(eta-C5H4)] (Ar = C6H5 (3a), Fc (3b), respectively). Os3(CO)7(H)(PPr(i))[Fe(eta-C5H4PPr(i)2)(eta-C5H4)] (4) is a product of the thermolysis of Os3(CO)10[Fe(eta-C5H4PPr(i)2)2]. 3b: triclinic, space group P1BAR (No. 2), a = 13.878 (2) angstrom, b = 14.145 (3) angstrom, c = 10.698 (2) angstrom, alpha = 104.28 (1)-degrees, beta = 110.88 (1)-degrees, gamma = 63.91 (1)-degrees. 3a: monoclinic, space group P2(1)/c (No. 14), a = 9.484 (3) angstrom, b = 18.144 (4) angstrom, c = 17.421 (3) angstrom, beta = 90.10 (2)-degrees. 4: monoclinic, space group P2(1)/n (No. 14), a = 8.910 (3) angstrom, b = 22.784 (2) angstrom, c = 15.416 (2) angstrom, beta = 98.25 (2)-degrees. The complexes are electron precise if the Fe --> Os bonds of length 2.830 (1) (3a), 2.826 (1) (3b), and 2.813 (1) angstrom (4) are included.

  DOI：

  10.1021/om00037a050