sulphito tri-ammino palladium | 40694-81-3

• 英文名称: sulphito tri-ammino palladium
• 英文别名: azane;palladium(2+);sulfite
• CAS: 40694-81-3
• 化学式: H₉N₃O₃PdS
• 分子量: 237.576
• InChiKey: LHRUQVPVMAPVHL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.52
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  85.4
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  [Pd(NH3)4][cis-diamminedichloride palladium(II)][Pd(NH3)3(SO3)]*H2O 以 水 为溶剂， 生成 sulphito tri-ammino palladium
  参考文献：
  名称：

  摘要：

  new palladium compound [Pd(NH3)(4)][cis-Pd(NH3)(2)(SO3)(2)][Pd(NH3)(3)(SO3)] . H2O (I) was synthesized and its structure was studied by X-ray powder diffraction method. In the course of the synthesis, the initial trans-diamminesulfite anionic complex is transformed into the cis-configuration. Further heating in aqueous solution results in isomerization of a substance into a neutral complex [Pd(NH3)(3)(SO3)]. Crystals I are triclinic: a = 10.3297(2) Angstrom, b = 14.1062(3) Angstrom, c = 6.853 1(1) Angstrom, alpha = 101.36(0)degrees, beta = 92.74(0)degrees, gamma = 92.71(0)degrees, space group P (1) over bar. Structure I consists of the columns with alternating cis-[pd(NH3)(2)(SO3)(2)](2-) and [Pd(NH3)(3)(SO3)] complexes and [Pd(NH3)(4)](2+) ions between the columns.

  DOI：

  10.1023/a:1023360723314

文献信息

• Vibrational spectra of group VIII sulphito complexes
  作者：J.P. Hall、W.P. Griffith

  DOI：10.1016/s0020-1693(00)90068-9

  日期：1981.1

  and infrared spectra are reported for Pd(SO 3 )(NH 3 ) 3 and salts containing [Ir(SO 3 ) 2 )Cl 4 ] 5− [Ir(SO 3 ) 2 (NH 3 ) 2 Cl 2 ] 3− , [Rh(SO 3 ) 3 (NH 3 ) 3 ] 3− , [Ir(SO 3 ) 3 (NH 3 ) 3 ] 3− , [Pt(SO 3 ) 4 ] 6− , [Ir(SO 3 ) 4 Cl 2 ] 7− and [OsO 2 (SO 3 ) 4 ] 6− . The results suggests that these contain metal—sulphur bonds and this also appears to be the case for the new complexes Os(SO 3 )(NH 3

  摘要报道了Pd（SO 3）（NH 3）3和含[Ir（SO 3）2）Cl 4] 5− [Ir（SO 3）2（NH 3）2 Cl 2] 3的盐的拉曼光谱和红外光谱。 -，[Rh（SO 3）3（NH 3）3] 3−，[Ir（SO 3）3（NH 3）3] 3−，[Pt（SO 3）4] 6−，[Ir（SO 3） ）4 Cl 2] 7-和[OSO 2（SO 3）4] 6-。结果表明它们含有金属硫键，对于新的配合物OS（SO 3）（NH 3）4 Cl，[OS（SO 3）3（H 2 O）3] 4−似乎也是如此。和[OS 2 N（SO 3）（NH 3）8（H 2 O）] 3+。所有这些的光谱与已知包含FeO键的[Fe（OSO 2）6] 9-的光谱有很大不同。