| 183298-35-3

• CAS: 183298-35-3
• 化学式: C₂₆H₃₃W₂*F₆P
• 分子量: 858.212
• InChiKey: FRUMPKQYQFRGLC-PTERYSDOSA-N

反应信息

• 作为反应物：
  描述：

  在 NaBH₄ 作用下， 以 not given 为溶剂， 以61%的产率得到
  参考文献：
  名称：

  Oxidatively induced carbon chain growth at a ditungsten centre

  摘要：

  X-Ray structural and EHMO studies show that two electrons are sequentially removed from a W-W delta* orbital on oxidation of the bis(metallacyclopentadiene) complex [W-2(mu-C(4)Me(4))(2)(eta-C5H5)(2)] to [W-2(mu-C(4)Me(4))(2)(eta-C5H5)(2)](z+) (z = 1, 2); the dication undergoes C-C coupling and proton loss in boiling MeCN to give [W-2(mu-C(8)Me(7)CH(2))(eta-C5H5)(2)](+) which adds hydride ion to form the metallacyclononatetraene complex [W-2(mu-C(8)Me(8))(eta-C5H5)(2)].

  DOI：

  10.1039/cc9960001877
• 作为产物：
  描述：

  以 乙腈 为溶剂， 以46%的产率得到
  参考文献：
  名称：

  Oxidatively induced carbon chain growth at a ditungsten centre

  摘要：

  X-Ray structural and EHMO studies show that two electrons are sequentially removed from a W-W delta* orbital on oxidation of the bis(metallacyclopentadiene) complex [W-2(mu-C(4)Me(4))(2)(eta-C5H5)(2)] to [W-2(mu-C(4)Me(4))(2)(eta-C5H5)(2)](z+) (z = 1, 2); the dication undergoes C-C coupling and proton loss in boiling MeCN to give [W-2(mu-C(8)Me(7)CH(2))(eta-C5H5)(2)](+) which adds hydride ion to form the metallacyclononatetraene complex [W-2(mu-C(8)Me(8))(eta-C5H5)(2)].

  DOI：

  10.1039/cc9960001877