trans-[manganese(II)(2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1,(18),2,12,14,16-pentaene)(μ1,3-azido)]PF6 | 286386-22-9

• 英文名称: trans-[manganese(II)(2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1,(18),2,12,14,16-pentaene)(μ1,3-azido)]PF6
• CAS: 286386-22-9
• 化学式: C₁₅H₂₃MnN₈*F₆P
• 分子量: 515.303
• InChiKey: SSXOBJRDQQOLSL-YBRXSBAKSA-N

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 sodium azide 、 [(2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene)diaquamanganese(II)] dichloride tetrahydrate 以 水 为溶剂， 生成 trans-[manganese(II)(2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1,(18),2,12,14,16-pentaene)(μ1,3-azido)]PF6
  参考文献：
  名称：

  Example of a single trans-azido-bridged Mn(II) chain: synthesis, structural and magnetic characteristics

  摘要：

  The synthesis of a trans coordinated 1-D mu(1,3)-azido-Mn(II) chain compound of the formula [Mn(L)(N-3)PF6](n), (L = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo{12.3.1}octadeca-1,(18),2,12,14,16-pentaene) is reported. Its crystal structure consists of 1-D arrays of Mn(II) units linked by single End-to-End azido bridges in trans position. Magnetic susceptibility measurements indicate tong range antiferromagnetic correlation between the Mn(II) centres below 30 K (J = - 4.8 cm(-1), H = - J Sigma SiSi + 1). The solid state EPR behaviour confirms that [Mn(L)(N-3)PF6](n) consists of 1-D Mn(II) arrays magnetically well isolated from the neighbouring chains. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00607-6