bis-rhodium(I)-3,4,8,9,12,13,16,17,21,22,25,26-dodecamethylamethyrin-tetracarbonyl | 203736-49-6

• 英文名称: bis-rhodium(I)-3,4,8,9,12,13,16,17,21,22,25,26-dodecamethylamethyrin-tetracarbonyl
• CAS: 203736-49-6
• 化学式: C₄₂H₄₀N₆O₄Rh₂
• 分子量: 898.628
• InChiKey: IGSOVGDAECJUDT-TWAURDOHSA-N

反应信息

• 作为产物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 amethyrin 在 三乙胺 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 以41%的产率得到bis-rhodium(I)-3,4,8,9,12,13,16,17,21,22,25,26-dodecamethylamethyrin-tetracarbonyl
  参考文献：
  名称：

  Synthesis and X-ray Crystallography of Rh(I) Carbonyl Complexes of Amethyrin

  摘要：

  The synthesis and characterization of two rhodium(I)dicarbonyl amethyrin complexes (mono and bis) are presented. X-ray structural results reveal that the amethyrin ligand undergoes significant distortion from planarity as the result of metal complexation and that, in the case of the bis-rhodium complex, the two metal centers lie on the same side of the mean ligand plane.

  DOI：

  10.1021/ic971018m