2-t-butyl-5,6-dihydro-4-phenylbenzochromenylium tetrafluoroborate | 73286-95-0

• 英文名称: 2-t-butyl-5,6-dihydro-4-phenylbenzochromenylium tetrafluoroborate
• CAS: 73286-95-0
• 化学式: BF₄*C₂₃H₂₃O
• 分子量: 402.24
• InChiKey: XAIXWGXECWQEAW-UHFFFAOYSA-N

物化性质

• 熔点：
  178-179 °C

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-t-butyl-5,6-dihydro-4-phenylbenzochromenylium tetrafluoroborate 在 三(羟基甲基)磷化氢 作用下， 生成 2-tert.-Butyl-4-phenyl-5,6-dihydro-naphtho<1,2-b>phosphorin
  参考文献：
  名称：

  Synthese und kristallstruktur von 2-tert-butyl-4-aryl-5.6-dihydro-naphtho- 1.2 -b -Phosphorin.

  摘要：

  DOI：

  10.1016/s0040-4039(00)70837-9
• 作为产物：
  描述：

  4,4-二甲基-1-苯基-1-戊烯-3-酮 、 3,4-二氢-1(2H)-萘酮 在 三氟化硼乙醚 作用下， 反应 6.0h， 以72%的产率得到2-t-butyl-5,6-dihydro-4-phenylbenzochromenylium tetrafluoroborate
  参考文献：
  名称：

  Katritzky, Alan R.; Marson, Charles M.; Thind, Sukhpal S., Journal of the Chemical Society. Perkin transactions I, 1983, p. 487 - 496

  摘要：

  DOI：

文献信息

• Alkylation of Monosubstituted Malonate Anions With Pyridinium and Quinolinium Salts
  作者：Alan R. Katritzky、Jose M. Aurrecoechea

  DOI：10.1055/s-1987-27938

  日期：——

  Monosubstituted malonate anions are alkylated at room temperature with 1-(sec-alkyl)quinolinium salts. Hindered disubstituted malonate esters can thus be prepared under very mild conditions.

  单取代的丙二酸盐在室温下与1-(次烷基)喹啉盐反应生成烷基化产物。因此，可以在非常温和的条件下制备出受阻的双取代丙二酸酯。
• The c-alkylation of nitroalkame anions by l-substituted-2--butyl-4-phenyl- and -2,4-diphenyl-5,6-dihydrobenzo(ulbarh]quinolinium cations
  作者：Alan R. Katritzky、M. Akram Kashmiri、Dieter K. Wittmann

  DOI：10.1016/s0040-4020(01)91797-1

  日期：1984.1

  - The N-substituents are transferred from the title cations to the C-atom of nitroalkane anions in high yield at 25-80°C in DMSO solution. The title cations are readily available from the appropriate pyrylium cations and primary amines of types RCH2,NH2, and RR'CHNH2, allowing a general 2-step method for the preparation of higher nitro- alkanes. Spectral properties of a variety of nitroalkanes are

  -在DMSO溶液中，在25-80°C下，高产率地将N-取代基从标题阳离子转移到硝基烷阴离子的C原子上。标题阳离子可容易地从合适的吡咯鎓阳离子和RCH 2，NH 2和RR'CHNH 2类型的伯胺获得，从而允许使用常规的两步法制备高级硝基烷。讨论了各种硝基烷的光谱性质。
• Kinetics and mechanisms of nucleophilic displacements with heterocycles as leaving groups. Part 6. Reactions of N-(substituted benzyl)azaheterocyclonium compounds with piperidine
  作者：Alan R. Katritzky、Wlodzimierz H. Basinski、Yu Xiang Ou、Giuseppe Musumarra、Ranjan C. Patel

  DOI：10.1039/p29820001055

  日期：——

  The preparation is described of series of N-(p-substituted)benzyl and N-(2-furfuryl) compounds with different heterocyclic leaving groups. First- and second-order rate constants for their reactions with piperidine in chlorobenzene are measured and discussed. Plots of k2 values for substituted compounds versus k2 for the parent N-benzyl derivative are linear for each substituent despite variable temperature

  描述了具有不同杂环离去基团的一系列N-（对位取代的）苄基和N-（2-糠基）化合物的制备。测量和讨论了它们在氯苯中与哌啶反应的一级和二级速率常数。尽管测量温度变化，但每个取代基的取代化合物的k 2值与母体N-苄基衍生物的k 2的关系图是线性的。
• Katritzky, Alan R.; Lloyd, Jeremy M.; Patel, Ranjan C., Journal of the Chemical Society. Perkin transactions I, 1982, p. 117 - 124
  作者：Katritzky, Alan R.、Lloyd, Jeremy M.、Patel, Ranjan C.

  DOI：——

  日期：——
• Kinetics and mechanisms of nucleophilic displacements with heterocycles as leaving groups. 2. N-benzylpyridinium cations: rate variation with steric effects in the leaving group
  作者：Alan R. Katritzky、Azzahra M. El-Mowafy、Giuseppe Musumarra、Kumars Sakizadeh、Choudhry Sana-Ullah、Sayed M. M. El-Shafie、Sukhpal S. Thind

  DOI：10.1021/jo00332a013

  日期：1981.9