| 429691-15-6

• CAS: 429691-15-6
• 化学式: C₄₄H₅₄CuN₈Ni₂O₁₀
• 分子量: 1035.89
• InChiKey: XCRLGFFNFOVUIU-KHFHVHCLSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 nickel(II) chloride hexahydrate 、 N,N'-bis(salicylidene)-2,2-dimethyl-1,3-diaminopropane 、 sodium nitrite 在 NH₄OH 作用下， 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Three heterotrinuclear Schiff base complexes of nickel(II) with cobalt(II), copper(II) and manganese(II)

  摘要：

  The title compounds, bis(dimethylformamide)-1kappaO,3kappaO-bis{mu-2,2'-[2,2'-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}-1kappa(4)N,N',O,O':2kappa(2)O,O';2kappa(2)O,O':3kappa(4)N,N',O,O'-di-mu-nitrito-1:2kappa(2) N:O;2:3kappa(2)O:N-dinickel(II)cobalt(II), [CoNi2(NO2)(2)(C19H22N2O2)(2)(C3H7NO)(2)], (I), -copper(II), [CuNi2(NO2)(2)(C19H22N2O2)(2)(C3H7NO)(2)], (II), and -manganese(II), [MnNi2(NO2)(2)(C19H22N2O2)(2)(C3H7NO)(2)], (III), consist of centrosymmetric linear heterotrinuclear metal complexes. The three complexes are isostructural. There are three bridges across the Ni-M atom pairs (M is Co2+, Cu2+ or Mn2+) in each complex, involving two O atoms of a mu-N,N'-bis(salicylidene)-2,2' dimethyl-1,3-propanediaminate ligand and an N-O moiety of a mu-nitrito group. The coordination sphere around each metal atom, whether Co2+, Cu2+, Mn2+ or Ni2+, can be described as distorted octahedral. The Ni...M distances are 2.9988 (5) Angstrom in (I), 2.9872 (5) Angstrom in (II) and 3.0624 (8) Angstrom in (III).

  DOI：

  10.1107/s0108270102001609