[Ru(η⁶-C₆Me₅H)Cl₂]₂ | 219650-68-7

• 英文名称: [Ru(η⁶-C₆Me₅H)Cl₂]₂
• 英文别名: [((η6-C6HMe5)RuCl)2(μ-Cl)2]；[(η6-C6HMe5)RuCl2]2
• CAS: 219650-68-7
• 化学式: C₂₂H₃₂Cl₄Ru₂
• 分子量: 640.448
• InChiKey: WXMYJVSAIHXSOR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(η⁶-C₆Me₅H)Cl₂]₂ 、 水 、 silver nitrate 反应 12.0h， 以97%的产率得到[Ru(H₂O)₃(η⁶-C₆Me₅H)](NO₃)₂
  参考文献：
  名称：

  Selective Redox Activation of H₂ or O₂ in a [NiRu] Complex by Aromatic Ligand Effects

  摘要：

  We present two closely related series of a [NiFe] hydrogenase analogue. Based on a [NiRu] core, these complexes demonstrate inactivity, H-2 activation, or O-2 activation depending only on the nature of the Ru-coordinated aromatic ligand. It is demonstrated that even small changes made to this aromatic ligand can modulate the catalytic activity of the complex. Structural, electrochemical, kinetic, and thermodynamic studies reveal that differences in activation and binding modes of the substrates, combined with differences in a donation and lability of the aromatic ligands, result in abrupt changes in catalytic activity.

  DOI：

  10.1021/om300833m

文献信息

• Cubane-Type Heterometallic Sulfido Clusters:  Incorporation of Two Metal Fragments into a Dinuclear ReS(μ-S)₂ReS Core Affording Bimetallic M₂Re₂(μ₃-S)₄ Clusters (M = Ru, Pt, Cu) or Trimetallic MM‘Re₂(μ₃-S)₄ Clusters via Incomplete Cubane-Type MRe₂(μ₃-S)(μ₂-S)₃ Intermediates (M = Ru, Rh, Ir; M‘ = Mo, W, Pd, Ru, Rh)
  作者：Hidetake Seino、Tetsuhide Kaneko、Shunpei Fujii、Masanobu Hidai、Yasushi Mizobe

  DOI：10.1021/ic030129k

  日期：2003.7.1

  nature of the metal complexes added. It has also been disclosed that the latter incomplete cubane-type clusters can serve as the good precursors to the trimetallic cubane-type clusters still poorly precedented. Thus, treatment of 5-7 with a range of metal complexes in THF at room temperature resulted in the formation of novel trimetallic cubane-type clusters, including the neutral clusters [[(eta(6)-

  四（硫代）络合物[PPh（4）]（2）[ReS（L）（mu-S）（2）ReS（L）]的反应（L = S（2）C（2）（SiMe（ 3））（2））与一系列在室温下在MeCN中的8-11组金属配合物提供了古巴型簇[M（2）（ReL）（2）（mu（3）-S）（4 ）]（M = CpRu（2），PtMe（3），Cu（PPh（3））（4）； Cp = eta（5）-C（5）Me（5））或不完全的古巴型簇[ M（ReL）（2）（mu（3）-S）（mu（2）-S）（3）]（M =（eta（6）-C（6）HMe（5））Ru（5， CpRh（6），CpIr（7）），取决于所添加金属络合物的性质。还已经公开了后一种不完全的古巴型簇可以作为尚不先进的三金属古巴型簇的良好前体。因此，在室温下用一系列金属络合物在THF中处理5-7会导致形成新型三金属古巴型簇，包括中性簇[[（eta（6）-C（6）HMe（5））Ru]
• η⁶-Coordination of the Curved Carbon Surface of Corannulene (C₂₀H₁₀) to (η⁶-arene)M²⁺ (M = Ru, Os)
  作者：Bolin Zhu、Arkady Ellern、Andrzej Sygula、Renata Sygula、Robert J. Angelici

  DOI：10.1021/om0610795

  日期：2007.3.1

  Reactions of [(eta(6)-arene)M(acetone)(3)]X-2 (M = Ru, Os; X = BF4, PF6, or SbF6) with 1 equiv of the curved-surface buckybowl, corannulene (C20H10, 1), in CD3NO2 afford quantitatively the eta(6)-coordinated complexes [(eta(6)-C6Me6)Ru(eta(6)-C20H10)]X-2 (3a, X = SbF6; 3b, X = PF6; 3c, X = BF4), [(eta(6)-C6HMe5)Ru(eta(6)-C20H10)](SbF6)(2) (4), [(eta(6)-C6EtMe5)Ru(eta(6)-C20H10)](SbF6)(2) (5), and [(eta(6)-cymene)Os(eta(6)-C20H10)](SbF6)(2) (6). In the solid state, yellow complexes 3-6 are stable in dry air for several months and have all been characterized by their H-1, C-13H-1}, and COSY NMR, mass spectra, elemental analyses, and X-ray diffraction; the corannulene in the complexes is slightly flattened as compared with free corannulene, 1. Even in the presence of excess [(eta(6)-arene)M(acetone)(3)]X-2, it was not possible to add two (eta(6)-arene)M2+ units to 1. The corannulene ligand in 3a is susceptible to nucleophilic attack by phosphines to give a mixture of adducts.