[(eta.5-C5H5)Ru(PPh3)2(μ-I)GaI3] | 1007348-04-0

• 英文名称: [(eta.5-C5H5)Ru(PPh3)2(μ-I)GaI3]
• CAS: 1007348-04-0
• 化学式: C₄₁H₃₅GaI₄P₂Ru
• 分子量: 1268.09
• InChiKey: OKJOSLJSIXGCRQ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氢化镓 、 二(三苯基膦)环戊二烯基氯化钌(II) 、 碘 、 甲苯 以 甲苯 为溶剂， 以42%的产率得到[(eta.5-C5H5)Ru(PPh3)2(μ-I)GaI3]
  参考文献：
  名称：

  Reactions of ‘GaI’ with organometallic transition metal halides

  摘要：

  Two approaches towards the synthesis of phosphine ligated half-sandwich complexes [(eta(x)-CxHx)M(PR3)(2)GaI2](n) containing diiodogallyl ligands have been investigated. Insertion. of 'Gal' into the Mo - I bond of (eta(7)-C7H7)Mo(CO)(2)I has been shown to yield the crystallographically characterized dimeric complex [(eta(7)-C7H7)Mo(CO)(2)GaI2](2) (2). Attempts to substitute the carbonyl ligands by the phosphine ligand dppe [dppe = bis(diphenylphosphino)ethane] have been shown instead to yield the sparingly soluble complex [(eta(7)-C7H7)Mo(CO)(2)GaI2](2)(mu-dppe) (3) in which the phosphine bridges two [(eta(7)-C7H7)Mo(CO)(2)GaI2] units via a pair of P -> Ga donor/acceptor bonds. By contrast, attempts to insert 'Gal' directly into the metal-halogen bond of phosphine ligated complexes such as (eta(5)-C5H5)Ru(PPh3)(2)Cl or (eta(5)-C5H5)Ru(dppe)Cl have been shown to result in the formation of the tetraiodogallate species (eta(5)-C5H5)Ru(PPh3)(2)(mu-I)GaI3 (5) and [(eta(5)-C5H5)Ru(dppe)](+)[GaI4](-) (7). (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.02.037