| 461052-90-4

• CAS: 461052-90-4
• 化学式: C₂₀H₃₆Cl₂PRh
• 分子量: 481.291
• InChiKey: BPBRXHLENJICEF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸 、 [Rh(μ-Cl)(C2H4)(2,6-Me2C6H3CH2CH2PtBu2-κP)]2 以 二氯甲烷 为溶剂， 以83%的产率得到[Rh(μ-Cl)Cl(C2H5)(2,6-Me2C6H3CH2CH2PtBu2-κP)]2
  参考文献：
  名称：

  An Unprecedented Dinuclear Alkylrhodium(III) Complex Built up by Two 14-Electron [RhCl₂(alkyl)(PR₃)] Units

  摘要：

  Reaction of HCl with [RhCl(C2H4)(PR3)]2 affords the dinuclear alkylrhodium(III) complex [RhCl2(C2H5)(PR3)]2, the structure of which has been determined crystallographically. PR3 is the formerly unknown trialkyl phosphine tBu2PCH2CH2C6H3-2,6-Me2, prepared in three steps from tBuPCl2. Treatment of the title compound with CO gives the mononuclear rhodium dicarbonyl cis-[RhCl(CO)2(PR3)], being the first fully characterized complex of this type.

  DOI：

  10.1021/ja020560t